Palladium-catalyzed annulation of monosubstituted β-diketones

被引：0
|
作者：
Buono, F [1 ]
Tenaglia, A [1 ]
机构：
[1] Fac Sci St Jerome, ENSSPICAM, Lab Synth Asymetr, UMR 6516, F-13397 Marseille 20, France
来源：
SYNLETT | 1998年 / 10期
关键词：
cycloalkanones; beta-diketones; C-C bond formation; palladium catalyst; annulation;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Various 4-methylenecyclohexanones and bridged bicyclo[3.n.1]alkanones (n = 2 or 3) are readily available via a palladium-catalyzed C,C-dialkylative cyclisation of monoalkylated beta-diketones with allylic diacetate 1a (or dicarbonate 1b). A one-pot bicycloannulation/retro Claisen fragmentation leading to medium-sized cycloalkanones from monoalkylated cyclic beta-diketones is described.
引用
收藏
页码：1153 / +
页数：4
相关论文
共 50 条
  • [1] Palladium-catalyzed annulation
    Larock, RC
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 576 (1-2) : 111 - 124
  • [2] Palladium-catalyzed annulation
    Larock, RC
    PURE AND APPLIED CHEMISTRY, 1999, 71 (08) : 1435 - 1442
  • [3] Palladium-Catalyzed Annulation of Arylbenzamides with Diaryliodonium Salts
    Pan, Cheng
    Wang, Limin
    Han, Jianwei
    ADVANCED SYNTHESIS & CATALYSIS, 2022, 364 (02) : 268 - 273
  • [4] Palladium-catalyzed annulation of vinylic cyclopropanes and cyclobutanes
    Larock, RC
    Yum, EK
    TETRAHEDRON, 1996, 52 (08) : 2743 - 2758
  • [5] Palladium-Catalyzed Annulation of Aryltriazoles and Arylisoxazoles with Alkynes
    Yuan, Hairui
    Wang, Min
    Xu, Zhenghu
    Gao, Hongyin
    ADVANCED SYNTHESIS & CATALYSIS, 2019, 361 (18) : 4386 - 4392
  • [6] Palladium-catalyzed coupling of amides and cyclopropanols for the synthesis of γ-diketones
    Fang, Lili
    Jia, Shuqi
    Fan, Shuaixin
    Zhu, Jin
    CHEMICAL COMMUNICATIONS, 2023, 59 (69) : 10392 - 10395
  • [7] Palladium-catalyzed annulation of aryl heterocycles with strained alkenes
    Hulcoop, David G.
    Lautens, Mark
    ORGANIC LETTERS, 2007, 9 (09) : 1761 - 1764
  • [8] Construction of Phenanthridinone Skeletons through Palladium-Catalyzed Annulation
    Geng, Xin
    He, Heng
    Shatskiy, Andrey
    Stepanova, Elena V.
    Alvey, Gregory R.
    Liu, Jian-Quan
    Karkas, Markus D.
    Wang, Xiang-Shan
    JOURNAL OF ORGANIC CHEMISTRY, 2023, 88 (17): : 12738 - 12743
  • [9] Palladium-Catalyzed Dual Annulation: A Method for the Synthesis of Norneocryptolepine
    Yeh, Li-Hsuan
    Wang, Hung-Kai
    Pallikonda, Gangaram
    Ciou, Yu-Lun
    Hsieh, Jen-Chieh
    ORGANIC LETTERS, 2019, 21 (06) : 1730 - 1734
  • [10] Palladium-catalyzed annulation of internal alkynes in aqueous medium
    Ang, Wei Jie
    Tai, Chih-Hsuan
    Lo, Lee-Chiang
    Lam, Yulin
    RSC ADVANCES, 2014, 4 (10): : 4921 - 4929
12345