Multiple aromatic amination mediated by a diiron complex

被引：41

作者：

Avenier, Frederic ^{[3
]}

Goure, Eric ^{[2
]}

Dubourdeaux, Patrick ^{[1
]}

Seneque, Olivier ^{[2
,3
]}

Oddou, Jean-Louis

Pecaut, Jacques ^{[4
]}

Chardon-Noblat, Sylvie ^{[5
]}

Deronzier, Alain ^{[5
]}

Latour, Jean-Marc ^{[1
]}

机构：

[1] CEA, iRTSV, DSV, Lab Chim & Biol Met PMB, F-38054 Grenoble, France

[2] Univ Grenoble 1, Lab Chim & Biol Met, F-38054 Grenoble, France

[3] CNRS, LCBM, UMR 5249, F-38054 Grenoble, France

[4] CEA Grenoble, CEA UJF, UMR E3, Lab Chim Inorgan & Biol, F-38054 Grenoble 9, France

[5] Univ Grenoble 1, Dept Chim Mol, CNRS, UMR 5250,ICMG FR 2607, F-38041 Grenoble, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 04期

关键词：

amination; arenes; bridging ligands; iron; N; O ligands;

D O I：

10.1002/anie.200703580

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Stop-frame amination: A very efficient amine transfer reaction is mediated by a biomimetic diiron complex, giving both single and double insertions of a tosylamine group into a pendant benzyl group of the ligand (see structure). The mono-insertion product has been shown by X-ray crystallography and other physical methods to be a tosylanilinato diiron(III) complex. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：715 / 717

页数：3

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