Thermal degradation of poly(vinyl chloride) as a typical macromolecular reaction

被引：0
|
作者：
Kolesov, SV
Kulish, EI
Zaikov, GE
机构：
[1] Bashkortostan State Univ, Ufa 450074, Bashkortostan, Russia
[2] Russian Acad Sci, Emanuel Inst Biochem Phys, Moscow 119991, Russia
来源：
POLYMER SCIENCE SERIES A | 2003年 / 45卷 / 07期
关键词：
POLYVINYL-CHLORIDE; VINYL-CHLORIDE; CHEMICAL STABILIZATION; MODEL COMPOUNDS; CO-POLYMERS; STABILITY; KINETICS; PVC; POLYVINYL-CHLORIDE); DEHYDROCHLORINATION;
D O I：
暂无
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Using the polymer-analogous reaction of dehydrochlorination of vinyl chloride-based polymers in bulk and solution, typical effects of macromolecular reactions, namely, configurational, conformational, and supermolecular, were considered. It was shown that, under certain conditions, structural effects stipulate the kinetic laws and specific features of polymer degradation along with the chemical structure of its macromolecular chains (the presence of abnormal groups).
引用
收藏
页码：597 / 605
页数：9
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