Rh-catalyzed synthesis of helically chiral and ladder-type molecules via [2+2+2] and formal [2+1+2+1] cycloadditions involving C-C triple bond cleavage

被引：123
|
作者：
Tanaka, Ken [1 ]
Kamisawa, Akiyoshi [1 ]
Suda, Takeshi [1 ]
Noguchi, Keiichi [1 ]
Hirano, Masao [1 ]
机构：
[1] Tokyo Univ Agr & Technol, Grad Sch Engn, Instrumentat Analysis Ctr, Dept Appl Chem, Koganei, Tokyo 1848588, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 40期
关键词：
D O I：
10.1021/ja074914y
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We have developed highly enantioselective synthesis of functionalized helically chiral molecules via a Rh-catalyzed [2 + 2 + 2] cycloaddition and synthesis of ladder-type molecules via an unprecedented Rh-catalyzed formal [2 + 1 + 2 + 1] cycloaddition involving C-C triple bond cleavage.
引用
收藏
页码：12078 / +
页数：3
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