RETRACTED: Biomimetic total synthesis of (+)-himbacine (Retracted article. See vol. 17, pg. 3190, 2015)

被引：33
|
作者：
Tchabanenko, K [1 ]
Adlington, RM [1 ]
Cowley, AR [1 ]
Baldwin, JE [1 ]
机构：
[1] Univ Oxford, Chem Res Lab, Oxford OX1 3TA, England
来源：
ORGANIC LETTERS | 2005年 / 7卷 / 04期
关键词：
D O I：
10.1021/ol047676+
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
On treatment with trifluoroacetic acid butenolide 14 undergoes N-Boc deprotection and condensation followed by an iminium ion activated intramolecular Diels-Aider cycloaddition to give the (+)-himbacine precursor 11 on reductive work up. Compound 11 was converted into (+)-himbacine in four synthetic steps.
引用
收藏
页码：585 / 588
页数：4
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