RETRACTED: Biomimetic total synthesis of (+)-himbacine (Retracted article. See vol. 17, pg. 3190, 2015)

被引：33

作者：

Tchabanenko, K ^{[1
]}

Adlington, RM ^{[1
]}

Cowley, AR ^{[1
]}

Baldwin, JE ^{[1
]}

机构：

[1] Univ Oxford, Chem Res Lab, Oxford OX1 3TA, England

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 04期

关键词：

D O I：

10.1021/ol047676+

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

On treatment with trifluoroacetic acid butenolide 14 undergoes N-Boc deprotection and condensation followed by an iminium ion activated intramolecular Diels-Aider cycloaddition to give the (+)-himbacine precursor 11 on reductive work up. Compound 11 was converted into (+)-himbacine in four synthetic steps.

引用

页码：585 / 588

页数：4

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