Poly[(2,2′-bipyridine-κ2N,N′)(μ3-2,4,6-trimethylisophthalato-κ5O1,O1′:O1:O3,O3′)cadmium]

被引：0

作者：

Hou, Shao-Gang ^{[1
]}

Jin, Mei-Fang ^{[1
]}

机构：

[1] Anyang Inst Technol, Coll Chem & Environm Engn, Anyang 455000, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷

关键词：

METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; BUILDING-BLOCKS; NETWORKS;

D O I：

10.1107/S1600536811054183

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the crystal structure of the polymeric title complex, [Cd(C11H10O4)(C10H8N2)](n), the Cd-II cation is chelated by one 2,2-bipyridine ligand and two carboxyl groups from two trimethylisophthalate (TMIPA) anions, and is further coordinated by one carboxylate O atom from a third TMIPA anion, forming a distorted pentagonal-bipyramidal geometry. Each TMIPA anion bridges three Cd-II cations, forming polymeric complex sheets parallel to (001). Weak C-H center dot center dot center dot O hydrogen bonding occurs between adjacent sheets.

引用

页码：M84 / +

页数：12

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