Ru-doped transition metal catalysts for liquid-phase Fischer-Tropsch synthesis

被引：2

作者：

Markova, Mariia E. ^{[1
,2
]}

Gavrilenko, Alexandra V. ^{[1
]}

Stepacheva, Antonna A. ^{[1
]}

Matveeva, Valentina G. ^{[1
,2
]}

Sulman, Mikhail G. ^{[1
]}

Panfilov, Viktor I. ^{[3
]}

Sulman, Esther M. ^{[1
]}

机构：

[1] Tver State Tech Univ, A Nikitina Str 22, Tver 170026, Russia

[2] Tver State Univ, Zhelyabova Str 33, Tver 170100, Russia

[3] DI Mendeleev Univ Chem Technol Russia, Miusskaya Sq 9, Moscow 125047, Russia

来源：

REACTION KINETICS MECHANISMS AND CATALYSIS | 2020年 / 130卷 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

Fischer-Tropsch synthesis; Transition metals; Ruthenium; Hypercrosslinked polystyrene; Hydrothermal deposition; CROSS-LINKED POLYSTYRENE; CARBON-MONOXIDE; NICKEL METAL; XPS SPECTRA; HYDROGENATION; NANOPARTICLES; SUPPORT; DIOXIDE; OXIDE; DEOXYGENATION;

D O I：

10.1007/s11144-020-01800-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this paper the catalytic activity of the Ru-doped polymer-based catalysts synthesized by the hydrothermal deposition is described. The catalytic properties of the synthesized systems were studied in the liquid-phase Fischer-Tropsch synthesis for the production of liquid gasoline and diesel-range hydrocarbons. The catalysts showed high CO hydrogenating activity allowing more than 20% of CO conversion to be obtained for one cycle. The yield of liquid hydrocarbons (mainly linear C-5-C-13) was found to be more than 80%. The addition of the ruthenium to the commonly used Co, Ni, and Fe enhances both the catalytic activity and the yield of the liquid hydrocarbons. The catalysts seem to be stable for minimum 80 h on stream.

引用

页码：813 / 823

页数：11

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