Synthesis of a new optically active carbamoyl azide and its use as an aminating agent

被引：8
作者：
Del Signore, G [1 ]
Fioravanti, S [1 ]
Pellacani, L [1 ]
Tardella, PA [1 ]
机构：
[1] Univ Roma La Sapienza, Dipartimento Chim, I-00185 Rome, Italy
来源：
TETRAHEDRON | 2001年 / 57卷 / 21期
关键词：
amination; amino ketones; asymmetric reactions; oxazolines;
D O I：
10.1016/S0040-4020(01)00383-0
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The synthesis of a chiral carbamoyl azide derived from Oppolzer's sultam is described. The thermal and photochemical behaviour in the presence of simple alkenes as well as of masked ketones is also reported. Diastereoselective amination reactions have been observed giving different products. (C) 2001 Elsevier Science Ltd. All rights reserved.
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收藏
页码：4623 / 4627
页数：5
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