Autoluminescent Metal-Organic Frameworks (MOFs): Self-Photoemission of a Highly Stable Thorium MOF

被引：69

作者：

Andreo, Jacopo ^{[1
]}

Priola, Emanuele ^{[1
]}

Alberto, Gabriele ^{[1
]}

Benzi, Paola ^{[1
,2
]}

Marabello, Domenica ^{[1
,2
]}

Proserpio, Davide M. ^{[3
,4
]}

Lamberti, Carlo ^{[2
,5
,6
]}

Diana, Eliano ^{[1
,2
]}

机构：

[1] Univ Turin, Dept Chem, Via Pietro Giuria 7, I-10125 Turin, Italy

[2] Interdept Ctr Crystallog, CriSDi, Via Pietro Giuria 7, I-10125 Turin, Italy

[3] Univ Milan, Dipartimento Chim, Via Golgi 19, I-20133 Milan, Italy

[4] Samara State Tech Univ, SCTMS, Molodogvardeyskaya St 244, Samara 443100, Russia

[5] Univ Turin, Interdept NIS Ctr, Dept Phys, Via Pietro Giuria 1, I-10125 Turin, Italy

[6] Southern Fed Univ, Smart Mat Res Inst, Sladkova St 178-24, Rostov Na Donu 344090, Russia

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2018年 / 140卷 / 43期

关键词：

COORDINATION POLYMERS; SINGLE-CRYSTAL; CARBON-DIOXIDE; ROD PACKINGS; STORAGE; DESIGN; URANYL; LUMINESCENCE; SCINTILLATOR; COMPLEXES;

D O I：

10.1021/jacs.8b07113

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel thorium(IV) metal-organic framework (MOF), Th(2,6-naphtalenedicarboxylate)(2), has been synthesized via solvothermal reaction of thorium nitrate and 2,6-naphtalendicarboxilyc acid. This compound shows a new structural arrangement with an interesting topology and an excellent thermal resistance, as the framework is stable in air up to 450 degrees C. Most notably, this MOF, combining the radioactivity of its metal center and the scintillation property of the ligand, has been proven capable of spontaneous photon emission.

引用

页码：14144 / 14149

页数：6

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