Weakly Interacting Molecular Layer of Spinning C60 Molecules on TiO2 (110) Surfaces

被引：25
作者：
Sanchez-Sanchez, Carlos [1 ,3 ]
Lanzilotto, Valeria [2 ,4 ]
Gonzalez, Cesar [1 ]
Verdini, Alberto [2 ]
de Andres, Pedro L. [1 ]
Floreano, Luca [2 ]
Lopez, Maria F. [1 ]
Martin-Gago, Jose A. [1 ,5 ]
机构：
[1] CSIC, ICMM, Canto Blanco 28049, Spain
[2] CNR, IOM, Lab TASC, I-34149 Trieste, Italy
[3] Univ Seville, CSIC, Inst Ciencia Mat Sevilla, Seville 41092, Spain
[4] Univ Trieste, Dept Phys, I-34127 Trieste, Italy
[5] CSIC, INTA, Ctr Astrobiol, Torrejon De Ardoz 28850, Spain
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 24期
关键词：
electronic states; fullerenes; molecular dynamics; titanium dioxide; van der Waals interactions; C-60; ADSORPTION; SCIENCE;
D O I：
10.1002/chem.201200627
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The adsorption of C 60, a typical acceptor organic molecule, on a TiO 2 (110) surface has been investigated by a multitechnique combination, including van der Waals density functional calculations. It is shown that the adsorbed molecules form a weakly interacting molecular layer, which sits on the fivefold-coordinated Ti that is confined between the prominent bridging oxygen rows (see figure). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：7382 / 7387
页数：6
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