Crystallization of glasses in the MoO3-Bi2O3 system

被引：6

作者：

Iordanova, Reni ^{[1
]}

Milanova, Margarita ^{[1
]}

Stoyanova, Angelina ^{[2
]}

Iliev, Cvetoslav ^{[3
]}

机构：

[1] Bulgarian Acad Sci, Inst Gen & Inorgan Chem, G Bonchev Str Bl 11, BU-1113 Sofia, Bulgaria

[2] Med Univ Pleven, Dept Chem & Biochem, BU-5800 Pleven, Bulgaria

[3] Bulgarian Acad Sci, Inst Geol, BU-1113 Sofia, Bulgaria

来源：

GLASS - THE CHALLENGE FOR THE 21ST CENTURY | 2008年 / 39-40卷

关键词：

non-traditional glasses; bismuth molybdates; crystallization;

D O I：

10.4028/www.scientific.net/AMR.39-40.391

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

alpha-Bi2Mo3O12 and beta-Bi2Mo2O9 crystal phases have been synthesized by crystallization of a glass for a short time. Amorphous samples with the compositions corresponding to the alpha and beta bismuth molybdates have been obtained at high cooling rates (10(4)-10(5) K/s). XRD, DTA and SEM studies were performed to examine the phase formation, thermal behavior of the glasses and the microstructure of obtained crystalline products. By scanning electron microscopy it was shown that the obtained bismuth molybdates consist of dense agglomerates, containing uniform distributed crystals with submicron size.

引用

页码：391 / +

页数：2

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