Role of hydrogen peroxide in the synthesis of nitrogen heterocycle containing cobalt complexes

被引：8
|
作者：
Nath, Jayanta [1 ]
Kalita, Dipjyoti [1 ]
Baruah, Jubaraj B. [1 ]
机构：
[1] Indian Inst Technol Guwahati, Dept Chem, Gauhati 781039, Assam, India
来源：
POLYHEDRON | 2011年 / 30卷 / 15期
关键词：
Cobalt complexes; Nitrogen donor ligands; p-Toluene sulfonate; Hydrogen peroxide; Binuclear complex; GLUTAMINE SYNTHETASE; ESCHERICHIA-COLI; OXIDATION; DERIVATIVES; CATALYSTS; EPOXIDES; MONONUCLEAR; HYDROLYSIS; REDUCTION; DINUCLEAR;
D O I：
10.1016/j.poly.2011.07.010
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactions of Co(O2CCH3)(2)center dot 4H(2)O with the sodium salt of p-toluene sulfonic acid (NapTS) and pyridine (py) or 4-methylpyridine (4mepy) in the presence of hydrogen peroxide in methanol led to the formation of [Co(py)(3)(H2O)(3)](pTS)(2) or [Co(4mepy)(2)(H2O)(4)](pTS)(2)center dot MeOH. respectively. The coordination polymer [(Co(44'bpy)(H2O)(4))(pTS)(2)](n) (4,4'-bipyridine = 44'bpy) was obtained from the reaction of Co(O2CCH3)(2)center dot 4H(2)O with 44'bpy 44'bpy in the presence of NapTS. The reaction of Co(O2CCH3)(2)center dot 4H(2)O, 2,2'-bipyridine (22'bpy) and NapTS with hydrogen peroxide resulted in the formation of the dinuclear complex [Co-2(mu-OH)(2)(mu-O2CCH3)(O2CCH3)(2)(22'bpy)(2)](pTS). characterization of these complexes and the role of hydrogen peroxide in these reactions are discussed. Similar reactions with sodium sulfamate gave the mononuclear [Co(22'bpy)(2)(O2CCH3)]NH2SO3 center dot 2H(2)O complex and [Co-2(mu-OH)(2)(mu-O2CCH3)(O2CCH3)(2) (22'bpy)(2)](NH2SO3). (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2558 / 2563
页数：6
相关论文
共 50 条
  • [21] Silver-palladium catalysts for the direct synthesis of hydrogen peroxide
    Khan, Zainab
    Dummer, Nicholas F.
    Edwards, Jennifer K.
    PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2018, 376 (2110):
  • [22] Synthesis and characterization of insoluble cobalt(II), nickel(II), zinc(II) and palladium(II) Schiff base complexes: Heterogeneous catalysts for oxidation of sulfides with hydrogen peroxide
    Menati, Saeid
    Rudbari, Hadi Amiri
    Askari, Banafshe
    Farsani, Mostafa Riahi
    Jalilian, Fariba
    Dini, Ghasem
    COMPTES RENDUS CHIMIE, 2016, 19 (03) : 347 - 356
  • [23] Decomposition of hydrogen peroxide in presence of mixed ligand cobalt(II) and nickel(II) complexes as catalysts
    Shivankar, VS
    Thakkar, NV
    JOURNAL OF SCIENTIFIC & INDUSTRIAL RESEARCH, 2005, 64 (07): : 496 - 503
  • [24] Electrochemical Synthesis of Hydrogen Peroxide Enabled by Tri-Coordinated Cobalt Sites in Silicate-1 Zeolite
    Yu, Guanghua
    Jin, Yingying
    Zhou, Ye
    Xia, Jing
    Meng, Xiangmin
    Dai, Guoliang
    Wang, Jiong
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2025,
  • [25] Tailoring oxygenated groups of monolithic cobalt-nitrogen-carbon frameworks for highly efficient hydrogen peroxide production in acidic media
    Liu, Wenxian
    Feng, Jinxiu
    Yin, Ruilian
    Ni, Yifeng
    Zheng, Dong
    Que, Wenbin
    Niu, Xinxin
    Dai, Xiaojing
    Shi, Wenhui
    Wu, Fangfang
    Yang, Jintao
    Cao, Xiehong
    CHEMICAL ENGINEERING JOURNAL, 2022, 430
  • [26] A new method for controlling the synthesis of graphite oxide: The effect of hydrogen peroxide
    Bannov, A. G.
    Netskina, O. V.
    Nikityonok, O. V.
    Kurmashov, P. B.
    Golovakhin, V.
    Ukhina, A. V.
    Maskimovskiy, E. A.
    Gudyma, T. S.
    MATERIALS CHEMISTRY AND PHYSICS, 2025, 339
  • [27] Advances in the direct synthesis of hydrogen peroxide from hydrogen and oxygen
    Edwards, Jennifer K.
    Freakley, Simon J.
    Lewis, Richard J.
    Pritchard, James C.
    Hutchings, Graham J.
    CATALYSIS TODAY, 2015, 248 : 3 - 9
  • [28] Interaction of peroxynitrite and hydrogen peroxide with dinitrosyl iron complexes containing thiol ligands in vitro
    Lobysheva, II
    Serezhenkov, VA
    Vanin, AF
    BIOCHEMISTRY-MOSCOW, 1999, 64 (02) : 153 - 158
  • [29] PECULARITIES OF PRIMARY PEROXIDE DERIVATIVES SYNTHESIS OF REACTION OF FLUORINE-CONTAINING CARBONYL COMPOUNDS WITH HYDROGEN PEROXIDE
    Chapurkin, V. V.
    Medvedev, V. P.
    Chapurkin, S. V.
    IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA, 2015, 58 (10): : 21 - +
  • [30] Synthesis, characterization and performance of two new Co(II) complexes as electrocatalyst of hydrogen peroxide and trichloroacetic acid
    Zhuang, RuiRui
    Jian, FangFang
    Wang, KeFei
    JOURNAL OF MOLECULAR STRUCTURE, 2009, 938 (1-3) : 254 - 258
12345