Borate-modulated amorphous NiFeB nanocatalysts as highly active and stable electrocatalysts for oxygen evolution reaction

被引：16

作者：

Zhao, Yunrui ^{[1
]}

Ma, Fahao ^{[1
]}

Wang, Zeyan ^{[1
]}

Wang, Peng ^{[1
]}

Liu, Yuanyuan ^{[1
]}

Cheng, Hefeng ^{[1
]}

Dai, Ying ^{[2
]}

Zheng, Zhaoke ^{[1
]}

Huang, Baibiao ^{[1
]}

机构：

[1] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China

[2] Shandong Univ, Sch Phys, Jinan 250100, Peoples R China

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2022年 / 903卷

基金：

中国国家自然科学基金;

关键词：

Borate modulation; NiFeB; Amorphous; Oxygen evolution reaction; BORIDE HYBRID; EFFICIENT;

D O I：

10.1016/j.jallcom.2022.163741

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The design of non-precious metal borides electrocatalysts with high efficiency and high stability is critical but challenging for the development of electrochemical water oxidation. The morphology and electronic structure will largely determine the activity and stability for amorphous nickel-iron-based catalysts. Herein,we developed a series of amorphous borate-modulated NiFeB OER catalysts through a facile two-step method, including sodium borohydride reduction and low temperature annealing. Benefiting from the monopoly of core-shell nanoparticles and the modulation of the boron electronic structure, the obtained NiFeB NPs-300 exhibits an overpotential of 231 mV at 20 mA cm(-2) in 1 M KOH as well as excellent stability. This work might provide a new way to improve the performance of metal-borate electrocatalysts by modulating the boron electronic structure. (C) 2022 Elsevier B.V. All rights reserved.

引用

页数：7

共 41 条

[21] In situ coating amorphous boride on ternary pyrite-type boron sulfide for highly efficient oxygen evolution [J].

Li, Tingting ;

Jing, Tianyun ;

Rao, Dewei ;

Jia, Xiaotian ;

Zuo, Yunpeng ;

Kment, Stepan ;

Zboril, Radek .

JOURNAL OF MATERIALS CHEMISTRY A, 2021, 9 (20) :12283-12290

[22] A high-performance oxygen evolution electrocatalyst based on partially amorphous bimetallic cobalt iron boride nanosheet [J].

Li, Yao ;

Jiang, Xiaoli ;

Tang, Mengyi ;

Zheng, Qiaoji ;

Huo, Yu ;

Xie, Fengyu ;

Lin, Dunmin .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2020, 45 (53) :28586-28597

[23] Defective Carbon-CoP Nanoparticles Hybrids with Interfacial Charges Polarization for Efficient Bifunctional Oxygen Electrocatalysis [J].

Lin, Yunxiang ;

Yang, Li ;

Zhang, Youkui ;

Jiang, Hongliang ;

Xiao, Zijian ;

Wu, Chuanqiang ;

Zhang, Guobin ;

Jiang, Jun ;

Song, Li .

ADVANCED ENERGY MATERIALS, 2018, 8 (18)

[24] Amorphous NiFeB nanoparticles realizing highly active and stable oxygen evolving reaction for water splitting [J].

Liu, Guang ;

He, Dongying ;

Yao, Rui ;

Zhao, Yong ;

Li, Jinping .

NANO RESEARCH, 2018, 11 (03) :1664-1675

[25] Reduced Graphene Oxide-Wrapped Co9-xFexS8/Co,Fe-N-C Composite as Bifunctional Electrocatalyst for Oxygen Reduction and Evolution [J].

Liu, Teng ;

Yang, Fulin ;

Cheng, Gongzhen ;

Luo, Wei .

SMALL, 2018, 14 (10)

[26] Revealing the Synergy of Cation and Anion Vacancies on Improving Overall Water Splitting Kinetics [J].

Liu, Yang ;

Bui, Huong T. D. ;

Jadhav, Amol R. ;

Yang, Taehun ;

Saqlain, Shahid ;

Luo, Yongguang ;

Yu, Jianmin ;

Kumar, Ashwani ;

Wang, Hongdan ;

Wang, Lingling ;

Bui, Viet Q. ;

Kim, Min Gyu ;

Kim, Young Dok ;

Lee, Hyoyoung .

ADVANCED FUNCTIONAL MATERIALS, 2021, 31 (21)

[27] Surface Fluorination Engineering of NiFe Prussian Blue Analogue Derivatives for Highly Efficient Oxygen Evolution Reaction [J].

Ma, Fahao ;

Wu, Qian ;

Liu, Mu ;

Zheng, Liren ;

Tong, Fengxia ;

Wang, Zeyan ;

Wang, Peng ;

Liu, Yuanyuan ;

Cheng, Hefeng ;

Dai, Ying ;

Zheng, Zhaoke ;

Fan, Yuchen ;

Huang, Baibiao .

ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (04) :5142-5152

[28] Ni3B as a highly efficient and selective catalyst for the electrosynthesis of hydrogen peroxide [J].

Ma, Fahao ;

Wang, Shuhua ;

Liang, Xizhuang ;

Wang, Cong ;

Tong, Fengxia ;

Wang, Zeyan ;

Wang, Peng ;

Liu, Yuanyuan ;

Dai, Ying ;

Zheng, Zhaoke ;

Huang, Baibiao .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2020, 279

[29] Amorphous Cobalt Boride (Co2B) as a Highly Efficient Nonprecious Catalyst for Electrochemical Water Splitting: Oxygen and Hydrogen Evolution [J].

Masa, Justus ;

Weide, Philipp ;

Peeters, Daniel ;

Sinev, Ilya ;

Xia, Wei ;

Sun, Zhenyu ;

Somsen, Christoph ;

Muhler, Martin ;

Schuhmann, Wolfgang .

ADVANCED ENERGY MATERIALS, 2016, 6 (06)

[30] Benchmarking of oxygen evolution catalysts on porous nickel supports [J].

Peugeot, Adele ;

Creissen, Charles E. ;

Karapinar, Dilan ;

Huan Ngoc Tran ;

Schreiber, Moritz ;

Fontecave, Marc .

JOULE, 2021, 5 (05) :1281-1300

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