Synthesis of Janus cube containing Si-H moieties

被引：1
|
作者：
Egawa, Yasunobu [1 ,2 ]
Kobuna, Chika [1 ]
Takeda, Nobuhiro [1 ]
Unno, Masafumi [1 ]
机构：
[1] Gunma Univ, Grad Sch Sci & Technol, Dept Chem & Chem Biol, Kiryu, Gunma 3768515, Japan
[2] Kanagawa Univ, Fac Sci, Dept Chem, Tsuchiya 2946, Hiratsuka, Kanagawa 2591293, Japan
来源：
MENDELEEV COMMUNICATIONS | 2022年 / 32卷 / 01期
关键词：
siloxanes; octasilsesquioxanes; organosilicon compounds; Janus particle; TG-DTA; SELECTIVE SYNTHESIS; OCTASILSESQUIOXANE; SILSESQUIOXANES; ROUTE;
D O I：
10.1016/j.mencom.2022.01.010
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first representative of the Janus cube with hydrogen substituents was obtained from all-cis-[(BuSiO)-Si-i(OH)](4) by its capping with HSiCl3 followed by gentle hydrolysis causing internal condensation. The compound has an extremely low maximum loss temperature, which is approximately halfway between H8Si8O12 and (octaisobuty)octasilsesquioxane.
引用
收藏
页码：35 / 36
页数：2
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