Induced Intramolecularity: An Effective Strategy in Catalysis

被引：68

作者：

Tan, Kian L. ^{[1
]}

机构：

[1] Boston Coll, Merkert Chem Ctr, Dept Chem, Chestnut Hill, MA 02467 USA

来源：

ACS CATALYSIS | 2011年 / 1卷 / 08期

基金：

美国国家科学基金会;

关键词：

catalysis; intramolecular; reversible covalent; stereoselectivity; entropy; preassociation; C BOND FORMATION; HYDROXYL-DIRECTED METHANOLYSIS; ALPHA-HYDROXYCARBOXYLIC ACIDS; ENE CYCLIZATION PROCESS; INTERMOLECULAR HYDROACYLATION; DESYMMETRIZING HYDROFORMYLATION; REGIOSELECTIVE HYDROFORMYLATION; ORTHO-ARYLATION; BORIC-ACID; HOMOGENEOUS CATALYSIS;

D O I：

10.1021/cs2002302

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The use of reversibly formed covalent bonds to induce intramolecular reactions is a powerful way of controlling regio- and stereoselectivity, as well as accelerating reactions. Although this mode of activation was demonstrated in catalytic systems over 60 years ago, it is infrequently used in catalyst design. This review will focus on highlighting examples of reversible covalent bonding in organic catalysts as well as ligands for metal catalysis. A key aspect of this type of catalysis is that it is an entropically driven process, so it has the potential to be applied to a broad variety of reactions. Furthermore, this design element can be used in concert with more traditional forms of catalyst activation.

引用

页码：877 / 886

页数：10

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