Synthesis and dynamic structure of multinuclear Rh complexes of porphyrinoids

被引：31

作者：

Setsune, Jun-Ichiro ^{[1
]}

Toda, Masayuki ^{[1
]}

Yoshida, Takafumi ^{[2
]}

机构：

[1] Kobe Univ, Dept Chem, Grad Sch Sci, Nada Ku, Kobe, Hyogo 6578501, Japan

[2] Kobe Univ, Dept Frontier Res & Technol, Kobe, Hyogo, Japan

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 12期

关键词：

D O I：

10.1039/b717022j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Large porphyrinoids with three Rh(CO)(2) groups at their dipyrrin units shows two-step metal transposition through the macrocycle in solution and the equilibrium between the C(3v)-isomer and the C(s)-isomer depends on the solvent polarity.

引用

页码：1425 / 1427

页数：3

共 20 条

[1] First cryptand-like calixpyrrole: Synthesis, X-ray structure, and anion binding properties of a bicyclic[3,3,3]nonapyrrole
Bucher, C
Zimmerman, RS
Lynch, V
Sessler, JL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (39) : 9716 - 9717
[2] AMINOSILANES IN ORGANIC-SYNTHESIS - PREPARATION OF NEW EXPANDED PORPHYRIN LIGANDS AND BIMETALLIC TRANSITION-METAL COMPLEXES - CRYSTAL-STRUCTURE OF A TETRAPYRROLE MACROCYCLE DIRHODIUM COMPLEX
CARRE, FH
CORRIU, RJP
BOLIN, G
MOREAU, JJE
VERNHET, C
[J]. ORGANOMETALLICS, 1993, 12 (07) : 2478 - 2486
[3] Jones RA, 1996, TETRAHEDRON, V52, P8707
[4] Octaethylporphyrin and expanded porphyrin complexes containing coordinated BF2 groups
Köhler, T
Hodgson, MC
Seidel, D
Veauthier, JM
Meyer, S
Lynch, V
Boyd, PDW
Brothers, PJ
Sessler, JL
[J]. CHEMICAL COMMUNICATIONS, 2004, (09) : 1060 - 1061
[5] Synthesis and X-ray crystallography of Rh(I) carbonyl complexes of amethyrin
Sessler, JL
Gebauer, A
Guba, A
Scherer, M
Lynch, V
[J]. INORGANIC CHEMISTRY, 1998, 37 (08) : 2073 - +
[6] Synthetic expanded porphyrin chemistry
Sessler, JL
Seidel, D
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (42) : 5134 - 5175
[7] Calix[n]bispyrrolylbenzenes:: Synthesis, characterization, and preliminary anion binding studies
Sessler, JL
An, DQ
Cho, WS
Lynch, V
Marquez, J
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (07) : 2001 - 2011
[8] ROSARIN - A NEW, EASILY PREPARED HEXAPYRROLIC EXPANDED PORPHYRIN
SESSLER, JL
WEGHORN, SJ
MORISHIMA, T
ROSINGANA, M
LYNCH, V
LEE, V
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (21) : 8306 - 8307
[9] TURCASARIN, THE LARGEST EXPANDED PORPHYRIN TO DATE
SESSLER, JL
WEGHORN, SJ
LYNCH, V
JOHNSON, MR
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1994, 33 (14) : 1509 - 1512
[10] [48]dodecaphyrin-(1.0.1.0.1.0.1.0.1.0.1.0) and [64]hexadecaphyrin-(1.0.1.0.1.0.1.0.1.0.1.0.1.0.1.0): The largest cyclopolypyrroles
Setsune, J
Katakami, Y
Iizuna, N
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (38) : 8957 - 8958

← 1 2 →