Synthesis and dynamic structure of multinuclear Rh complexes of porphyrinoids

被引：31
|
作者：
Setsune, Jun-Ichiro [1 ]
Toda, Masayuki [1 ]
Yoshida, Takafumi [2 ]
机构：
[1] Kobe Univ, Dept Chem, Grad Sch Sci, Nada Ku, Kobe, Hyogo 6578501, Japan
[2] Kobe Univ, Dept Frontier Res & Technol, Kobe, Hyogo, Japan
来源：
CHEMICAL COMMUNICATIONS | 2008年 / 12期
关键词：
D O I：
10.1039/b717022j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Large porphyrinoids with three Rh(CO)(2) groups at their dipyrrin units shows two-step metal transposition through the macrocycle in solution and the equilibrium between the C(3v)-isomer and the C(s)-isomer depends on the solvent polarity.
引用
收藏
页码：1425 / 1427
页数：3
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