Application of Technical Kinetics for Macroscopic Analysis of Ozone Synthesis Process

被引:34
作者
Jodzis, Slawomir [1 ]
机构
[1] Warsaw Univ Technol, Fac Chem, PL-00662 Warsaw, Poland
关键词
TO-CYLINDER OZONIZER; AIR; GENERATION; OXYGEN; CORONA; OPTIMIZATION; DISCHARGE;
D O I
10.1021/ie102603z
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The method of measuring the technical rate of ozone synthesis process, and the manner of utilizing the process rate for determining the boundary ozone contents in the reacting system has been presented. On the basis of macroscopic analysis of the process the reason causing the obtaining of the ozone concentration lower than that theoretically possible, has been pointed out. It is shown that an increase in temperature in the discharge gap does not inhibit the ozone-forming rate. The decrease in ozone concentration observed is a result of ozone intensive decomposition. However, under typical conditions of the process, the ozone decomposition is a result of the temperature in the microdischarge channels and not that of the gas or the cooling liquid.
引用
收藏
页码:6053 / 6060
页数:8
相关论文
共 27 条
[1]  
AKISHEV YS, 1994, FIZ PLAZMY, V20, P571
[2]  
Benas J.M., 1991, P 10 OZ WORLD C MARC, V1, P15
[3]  
BES RS, 1987, OZONE-SCI ENG, V9, P247
[4]   Experimental study on ozone synthesis via dielectric barrier discharges [J].
Chang, MB ;
Wu, SJ .
OZONE-SCIENCE & ENGINEERING, 1997, 19 (03) :241-254
[5]   The rate constant for dissociative electron attachment to ozone revisited [J].
Cicman, P ;
Francis, M ;
Skalny, JD ;
Matejcik, S ;
Märk, TD .
CZECHOSLOVAK JOURNAL OF PHYSICS, 2003, 53 (03) :181-190
[6]   Ozone production and de-NOx modeling in dry air electrical discharges [J].
Deryugin, A ;
Napartovich, A ;
Gorse, C ;
Paniccia, F ;
Capitelli, M .
PLASMA CHEMISTRY AND PLASMA PROCESSING, 1997, 17 (01) :79-91
[7]   OZONE SYNTHESIS FROM OXYGEN IN DIELECTRIC BARRIER DISCHARGES [J].
ELIASSON, B ;
HIRTH, M ;
KOGELSCHATZ, U .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1987, 20 (11) :1421-1437
[8]   Analytic calculations of ozone concentration in an oxygen-fed wire-to-cylinder ozonizer and comparison with the Vasil'ev relation [J].
Held, B ;
Peyrous, R .
EUROPEAN PHYSICAL JOURNAL-APPLIED PHYSICS, 1998, 4 (01) :73-86
[10]   Analysis of ozone generation from air in silent discharge [J].
Kitayama, J ;
Kuzumoto, M .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1999, 32 (23) :3032-3040