Global analysis of data on the spin-orbit-coupled A 1Σu+ and b 3Πu states of Cs2

被引：42

作者：

Bai, Jianmei ^{[1
]}

Ahmed, E. H. ^{[1
]}

Beser, B. ^{[1
]}

Guan, Y. ^{[1
]}

Kotochigova, S. ^{[1
]}

Lyyra, A. M. ^{[1
]}

Ashman, S. ^{[2
]}

Wolfe, C. M. ^{[2
]}

Huennekens, J. ^{[2
]}

Xie, Feng ^{[3
,4
]}

Li, Dan ^{[3
,4
]}

Li, Li ^{[3
,4
]}

Tamanis, M. ^{[5
]}

Ferber, R. ^{[5
]}

Drozdova, A. ^{[6
]}

Pazyuk, E. ^{[6
]}

Stolyarov, A. V. ^{[6
]}

Danzl, J. G. ^{[7
,8
]}

Naegerl, H-C. ^{[7
,8
]}

Bouloufa, N. ^{[9
]}

Dulieu, O. ^{[9
]}

Amiot, C. ^{[9
]}

Salami, H. ^{[10
]}

Bergeman, T. ^{[10
]}

机构：

[1] Temple Univ, Dept Phys, Philadelphia, PA 19122 USA

[2] Lehigh Univ, Dept Phys, Bethlehem, PA 18015 USA

[3] Tsinghua Univ, Dept Phys, Beijing 100084, Peoples R China

[4] Tsinghua Univ, Key Lab Atom & Mol Nanosci, Beijing 100084, Peoples R China

[5] Univ Latvia, Dept Phys, Ctr Laser, LV-1586 Riga, Latvia

[6] Moscow MV Lomonosov State Univ, Dept Chem, RU-119992 Moscow, Russia

[7] Univ Innsbruck, Inst Expt Phys, A-6020 Innsbruck, Austria

[8] Univ Innsbruck, Zentrum Quantenphys, A-6020 Innsbruck, Austria

[9] Univ Paris 11, CNRS, Aime Cotton Lab, F-91405 Orsay, France

[10] SUNY Stony Brook, Dept Phys & Astron, Stony Brook, NY 11794 USA

来源：

PHYSICAL REVIEW A | 2011年 / 83卷 / 03期

基金：

美国国家科学基金会;

关键词：

TRIPLE-RESONANCE SPECTROSCOPY; RESOLUTION LASER SPECTROSCOPY; HYPERFINE-STRUCTURE; 3-PI-U STATES; PERTURBATION; SPECTRA; POLARIZATION; MOLECULES; FLUORESCENCE; LI-6(2);

D O I：

10.1103/PhysRevA.83.032514

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

We present experimentally derived potential curves and spin-orbit interaction functions for the strongly perturbed A (1)Sigma(+)(u) and b (3)Pi(u) states of the cesium dimer. The results are based on data from several sources. Laser-induced fluorescence Fourier transform spectroscopy (LIF FTS) was used some time ago in the Laboratoire Aim'e Cotton primarily to study the X (1)Sigma(+)(g) state. More recent work at Tsinghua University provides information from moderate resolution spectroscopy on the lowest levels of the b (3)Pi(+/-)(0u) state as well as additional high-resolution data. From Innsbruck University, we have precision data obtained with cold Cs-2 molecules. Recent data from Temple University was obtained using the optical-optical double resonance polarization spectroscopy technique, and finally, a group at the University of Latvia has added additional LIF FTS data. In the Hamiltonian matrix, we have used analytic potentials (the expanded Morse oscillator form) with both finite-difference (FD) coupled-channel and discrete variable representation (DVR) calculations of the term values. Fitted diagonal and off-diagonal spin-orbit functions are obtained and compared with ab initio results from Temple and Moscow State universities.

引用

页数：17

共 93 条

[1] Coherent Transfer of Photoassociated Molecules into the Rovibrational Ground State [J].