Insight into Water-Soluble Highly Fluorescent Low-Dimensional Host-Guest Supramolecular Polymers: Structure and Energy-Transfer Dynamics Revealed by Polarized Fluorescence Spectroscopy

被引:13
作者
Nandajan, Paramjyothi C. [1 ]
Kim, Hyeong-Ju [2 ]
Casado, Santiago [1 ]
Park, Soo Young [2 ]
Gierschner, Johannes [1 ]
机构
[1] Madrid Inst Adv Studies, IMDEA Nanosci, Calle Faraday 9,Campus Cantoblanco, Madrid 28049, Spain
[2] Seoul Natl Univ, Dept Mat Sci & Engn, Ctr Supramol Optoelect Mat, ENG 445, Seoul 151744, South Korea
基金
新加坡国家研究基金会;
关键词
OLIGOTHIOPHENE INCLUSION-COMPOUNDS; MOLECULAR RECOGNITION; ORGANIC FRAMEWORK; CHEMISTRY; OLIGOPHENYLENEVINYLENES; FILMS; ARCHITECTURES; LUMINESCENCE; NANOCHANNELS; ENHANCEMENT;
D O I
10.1021/acs.jpclett.8b01562
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Water-soluble, highly fluorescent host guest chromophore-cucurbit[8]uril supramolecular polymer bundles are investigated by polarized time-resolved photoluminescence spectroscopy, structural methods, and quantum chemistry to fully reveal structural organization and heterogeneity but, in particular, energy-transfer dynamics, being of crucial importance for the design of supramolecular artificial light-harvesting systems.
引用
收藏
页码:3870 / 3877
页数:15
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