Numerical simulation of water droplet dynamics in a right angle gas channel of a polymer electrolyte membrane fuel cell

被引:54
作者
Jo, Jae Hyuk [1 ]
Kim, Woo Tae [1 ]
机构
[1] Kongju Natl Univ, Dept Mech & Automot Engn, Cheonan 331717, Chungnam, South Korea
基金
新加坡国家研究基金会;
关键词
Polymer electrolyte membrane fuel; cell; Water management; Water droplet dynamics; Two-phase flow; Volume of fluid method; LATTICE BOLTZMANN METHOD; LIQUID WATER; FLOW CHANNELS; DIFFUSION LAYER; 2-PHASE FLOW; CATHODE SIDE; TRANSPORT; MODEL; ACCUMULATION; PERFORMANCE;
D O I
10.1016/j.ijhydene.2015.04.122
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The dynamics of liquid water emerging from a micro pore on a gas diffusion layer (GDL) surface into a right angle gas channel of a polymer electrolyte membrane (PEM) fuel cell is investigated numerically with the volume of fluid method. As the GDL surface contact angle decreases, droplets from the outer and inner pores tend to move along the side walls or the lower edges and droplets from the center pore show complex patterns of behavior. As the hydrophobicity of the side and top walls increases, the GDL surface water coverage ratio increases, while the water volume fraction decreases. While the higher GDL surface water coverage ratio hinders the diffusion of reactants to reaction sites, the lower water volume fraction is advantageous in preventing water flooding in the gas channel. Therefore, in general gas channel geometry, the GDL surface water coverage ratio and the water volume fraction may compete with each other to determine the performance of PEM fuel cells, while changing the hydrophobicity of the side and top walls. As the air inlet velocity increases, liquid water moves faster and the water volume fraction decreases. As the water injection velocity increases, the moving speed of the water and the water volume fraction increase. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights
引用
收藏
页码:8368 / 8383
页数:16
相关论文
共 61 条
[51]   POLYMER ELECTROLYTE FUEL-CELL MODEL [J].
SPRINGER, TE ;
ZAWODZINSKI, TA ;
GOTTESFELD, S .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (08) :2334-2342
[52]   Dynamics of water droplets detached from porous surfaces of relevance to PEM fuel cells [J].
Theodorakakos, A. ;
Ous, T. ;
Gavaises, A. ;
Nouri, J. M. ;
Nikolopoulos, N. ;
Yanagihara, H. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2006, 300 (02) :673-687
[53]   In situ investigation of water transport in an operating PEM fuel cell using neutron radiography: Part 1 - Experimental method and serpentine flow field results [J].
Trabold, T. A. ;
Owejan, J. P. ;
Jacobson, D. L. ;
Arif, M. ;
Huffman, P. R. .
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2006, 49 (25-26) :4712-4720
[54]   Magnetic resonance imaging of the water distribution within a polymer electrolyte membrane in fuel cells [J].
Tsushima, S ;
Teranishi, K ;
Hirai, S .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (09) :A269-A272
[55]   Computational fluid dynamics modeling of proton exchange membrane fuel cells [J].
Um, S ;
Wang, CY ;
Chen, KS .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (12) :4485-4493
[56]   Liquid water flooding process in proton exchange membrane fuel cell cathode with straight parallel channels and porous layer [J].
Wang, Xichen ;
Zhou, Biao .
JOURNAL OF POWER SOURCES, 2011, 196 (04) :1776-1794
[57]   Two-phase flow and transport in the air cathode of proton exchange membrane fuel cells [J].
Wang, ZH ;
Wang, CY ;
Chen, KS .
JOURNAL OF POWER SOURCES, 2001, 94 (01) :40-50
[58]   Modeling transport in polymer-electrolyte fuel cells [J].
Weber, AZ ;
Newman, J .
CHEMICAL REVIEWS, 2004, 104 (10) :4679-4726
[59]   Visualization of liquid water transport in a PEFC [J].
Yang, XG ;
Zhang, FY ;
Lubawy, AL ;
Wang, CY .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (11) :A408-A411
[60]   Characteristics of droplet and film water motion in the flow channels of polymer electrolyte membrane fuel cells [J].
Zhan, Zhigang ;
Xiao, Jinsheng ;
Pan, Mu ;
Yuan, Runzhang .
JOURNAL OF POWER SOURCES, 2006, 160 (01) :1-9