Understanding the impact of ionic liquid pretreatment on biomass and enzymatic hydrolysis

被引:92
作者
Tan, Hui Teng [1 ]
Lee, Keat Teong [1 ]
机构
[1] Univ Sains Malaysia, Lignocellulos Res Grp, Sch Chem Engn, Nibong Tebal 14300, Pulau Pinang, Malaysia
关键词
Oil palm frond; Ionic liquid pretreatment; Lignin; Cellulose; Hemicellulose; Digestibility; CELLULOSE; DISSOLUTION; WOOD; LIGNIN; ACID; SACCHARIFICATION; DELIGNIFICATION; RECALCITRANCE;
D O I
10.1016/j.cej.2011.12.086
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The chemical and physical changes of lignocellulosic biomass after subjecting to various pretreatment conditions were investigated in this current work. Subsequently, the effects of biomass changes on digestibility of cellulose to fermentable sugar (glucose) by enzyme were studied. Oil palm frond (OPF), the chosen biomass in this study was pretreated using ionic liquid (IL) 1-butyl-3-methylimidazolium chloride ([BMIM]Cl) at different pretreatment conditions before subjected to analysis and subsequent enzymatic hydrolysis process. The pretreatment variables studied in this work are temperature, retention time and solid loading. Results showed that OPF experienced changes in lignin, cellulose and hemicellulose content after pretreatment due to dissolution as well as depolymerization process occurring during pretreatment. In addition to that, the recalcitrance of lignocellulosic biomass was effectively disrupted by ionic liquid pretreatment at various pretreatment conditions as cellulose digestibility of OPF was largely enhanced after pretreatment. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:448 / 458
页数:11
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