Synthesis and Properties of X-Type Alkyl Sulfonate Gemini Surfactants Derived from Cyanuric Chloride

被引：17

作者：

Li, Pengfei ^{[1
]}

Chen, Qihu ^{[1
]}

Zhao, Jiale ^{[1
]}

Wang, Hushan ^{[1
]}

Li, Chen ^{[1
]}

Hu, Zhiyong ^{[1
]}

Cao, Duanlin ^{[1
]}

机构：

[1] N Univ China, Sch Chem Engn & Environm, Taiyuan 030051, Shanxi, Peoples R China

来源：

JOURNAL OF SURFACTANTS AND DETERGENTS | 2012年 / 15卷 / 04期

关键词：

Gemini surfactants; Cyanuric chloride; Surface tension; Electrical conductivity; Thermodynamics of micellization; ALKANEDIYL-ALPHA; OMEGA-BIS(DIMETHYLALKYLAMMONIUM BROMIDE) SURFACTANTS; ANGLE NEUTRON-SCATTERING; DIMERIC SURFACTANTS; MICELLE FORMATION; SPACER CHAIN; WATER; MICELLIZATION; TEMPERATURE; ADSORPTION; BEHAVIOR;

D O I：

10.1007/s11743-011-1320-1

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A series of X-type alkyl sulfonate Gemini surfactants (XCn, n = 6, 8, 10) was synthesized by a simple method. The chemical structures of the prepared compounds were confirmed by H-1 NMR, C-13 NMR, ESI-MS and Elementary analysis. The surface activity and thermodynamic properties of micellization of the X-type alkyl sulfonate Gemini surfactants were compared with sodium dodecylsulfate by means of surface tension. The properties of XCn are superior to those of SDS such as the gamma(CMC) and CMC of XC10 are 26.3 mN/m and 0.2 mmol/L respectively. The adsorption isotherms for XCn were established by fitting the pre-CMC surface tension data with a quadratic function. The thermodynamic parameters of micellization (, , ) derived from electrical conductivity indicate that the micellization of XCn is entropy-driven.

引用

页码：449 / 456

页数：8

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