The Interaction of Nickel(II) and Copper(II) Schiff Base Complexes with Diorganotin(IV) Dichlorides in Acetonitrile: A Thermodynamic Study

被引：1

作者：

Asadi, Zahra ^{[1
]}

Asadi, Mozaffar ^{[1
]}

Mosalanezhad, Fatemeh ^{[1
]}

机构：

[1] Shiraz Univ, Coll Sci, Dept Chem, Shiraz 71454, Iran

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2011年 / 41卷 / 09期

关键词：

copper(II) complexes; diorganotin(IV) dichlorides; nickel(II) complexes; Schiff base; thermodynamic; TIN CHEMISTRY; DINUCLEAR ADDUCTS; LEWIS-ACIDS; LIGANDS; TIN(IV);

D O I：

10.1080/15533174.2011.591362

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Adduct formation of nickel(II) and copper(II) Schiff base complexes, (NiL) and (CuL), as donors with diorganotin(IV) dichlorides as acceptors has been investigated spectrophotometrically, in acetonitrile. L is alpha,alpha'-Me-2-salen, N,N'-ethylenebis(alpha-methylsalicylideneiminate) (1), alpha,alpha'-Me-2-salen, N,N'-1,2-propylenebis(alpha-methylsalicylideneiminate) (2), alpha,alpha'-Ph-2-salen, N,N'-ethylenebis(alpha-phenylsalicylideneiminate) (3), and alpha,alpha'-Ph-2-salen, N,N'-1,2-propylenebis(alpha-phenylsalicylideneiminate) (4). The trend of adduct formation of the nickel(II) and copper(II) Schiff base complexes with a given tin compound decreases as follows: M(alpha,alpha'-Me-2-salen) > M(alpha,alpha'-Me-2-salpn) > M(alpha,alpha'-Ph-2-salen) > M(alpha,alpha'-Ph-2-salpn). The trend of the reaction of R2SnCl2 toward a given nickel(II) or copper(II) Schiff base complex is Ph > Me > Bu. The trend of the metal reactivity in a given Schiff base toward a given diorganotin(IV) dichloride at the same temperature is Cu(II) > Ni(II).

引用

页码：1158 / 1166

页数：9

共 14 条

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