The antioxidant capacity and oxidative stability of virgin olive oil enriched with phospholipids

被引:79
作者
Koprivnjak, Olivera [1 ]
Skevin, Dubravka [2 ]
Valic, Srecko [3 ,4 ]
Majetic, Valerija [1 ]
Petricevic, Sandra [5 ]
Ljubenkov, Ivica [5 ]
机构
[1] Univ Rijeka, Sch Med, Dept Food Technol & Control, Rijeka 51000, Croatia
[2] Fac Food Technol & Biotechnol, Dept Food Technol Engn, Zagreb 10000, Croatia
[3] Rudjer Boskovic Inst, Zagreb 10000, Croatia
[4] Univ Rijeka, Sch Med, Dept Chem & Biochem, Rijeka 51000, Croatia
[5] Sms Food Dev Ctr, Klis 23231, Croatia
关键词
phospholipids; virgin olive oil; radical-scavenging activity; electron spin resonance spectroscopy; oxidative stability;
D O I
10.1016/j.foodchem.2008.03.045
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Virgin olive oil (VOO) enriched with phospholipids (soy lecithin) up to the levels present in seed oils (from 2.5 to 10.0 g/kg) was studied as a potential functional food. Lecithin addition slightly increased the concentration of tocopherols and considerably increased K270 values. In the fatty acid composition, an increase of linoleic and a slight decrease of oleic acid were observed, as the decrease of monounsaturated/polyunsaturated fatty acid ratio. The radical-scavenging activity was evaluated by two methods: electron spin resonance spectroscopy using galvinoxyl free radical and VIS spectroscopy measurement of the disappearance of 1,1-diphenyl-2-picryl-hydrazyl (DPPH) radical. Results indicate that lecithin addition retards the scavenging activity of VOO that is ascribed to the bipolar character of lecithin and its ability to entrap hydrophilic antioxidants. The effect of lecithin addition on the oxidative stability of VOO was evaluated by the Rancimat method, and a positive linear correlation (r = 0.9849) with induction time was found. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:121 / 126
页数:6
相关论文
共 20 条
[1]  
Bernardini E., 1983, OILSEEDS OILS FATS, VI, P173
[2]   Evaluation of the antioxidant capacity of individual phenolic compounds in virgin olive oil [J].
Carrasco-Pancorbo, A ;
Cerretani, L ;
Bendini, A ;
Segura-Carretero, A ;
Del Carlo, M ;
Gallina-Toschi, T ;
Lercker, G ;
Compagnone, D ;
Fernández-Gutiérrez, NG .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2005, 53 (23) :8918-8925
[3]   Characterization of the total free radical scavenger capacity of vegetable oils and oil fractions using 2,2-diphellyl-1-picrylhydrazyl radical [J].
Espín, JC ;
Soler-Rivas, C ;
Wichers, HJ .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2000, 48 (03) :648-656
[4]   Changes produced in the antioxidative activity of phospholipids as a consequence of their oxidation [J].
Hidalgo, FJ ;
Nogales, F ;
Zamora, R .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2005, 53 (03) :659-662
[5]   Antioxidative activity of amino phospholipids and phospholipid/amino acid mixtures in edible oils as determined by the Rancimat method [J].
Hidalgo, Francisco J. ;
Leon, M. Mercedes ;
Zamora, Rosario .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2006, 54 (15) :5461-5467
[6]  
ISO, 1997, 9936 ISO
[7]   Stability and radical-scavenging activity of heated olive oil and other vegetable oils [J].
Kalantzakis, G ;
Blekas, G ;
Pegklidou, K ;
Boskou, D .
EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY, 2006, 108 (04) :329-335
[8]   PHOSPHOLIPIDS INCREASE RADICAL-SCAVENGING ACTIVITY OF VITAMIN-E IN A BULK OIL MODEL SYSTEM [J].
KOGA, T ;
TERAO, J .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1995, 43 (06) :1450-1454
[9]   The contents of proteins and phospholipids in cloudy (veiled) virgin olive oils [J].
Koidis, A ;
Boskou, D .
EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY, 2006, 108 (04) :323-328
[10]   FACTOR FOR CONVERTING ELEMENTAL PHOSPHORUS TO ACETONE INSOLUBLES IN CRUDE SOYBEAN OIL [J].
LIST, GR ;
HEAKIN, AJ ;
EVANS, CD ;
BLACK, LT ;
MOUNTS, TL .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1978, 55 (06) :521-522