Luminescence, electrochemical and photocatalytic properties of sub-micron nickel(II) and cobalt(II) coordination polymers synthesized by sonochemical process

被引：47

作者：

Li, Jun Xuan ^{[1
]}

Li, Yu Feng ^{[1
]}

Liu, Li Wei ^{[1
]}

Cui, Guang Hua ^{[1
]}

机构：

[1] North China Univ Sci & Technol, Hebei Key Lab Environm Photocatalyt & Electrocata, Coll Chem Engn, Tangshan 063210, Hebei, Peoples R China

来源：

ULTRASONICS SONOCHEMISTRY | 2018年 / 41卷

基金：

中国国家自然科学基金;

关键词：

Coordination polymer; Crystal structure; 2D sub-micron sized nickel(II) and cobalt(II); Sonochemical method; Photocatalytic activity; 5-Methylisophthalic acid; METAL-ORGANIC FRAMEWORKS; SUPRAMOLECULAR POLYMER; MECHANOCHEMICAL CONVERSION; ULTRASONIC IRRADIATION; TOPOLOGICAL STRUCTURES; DIFFERENT MORPHOLOGIES; STRUCTURAL DIVERSITY; CRYSTAL-STRUCTURES; LIGANDS; FLUORESCENCE;

D O I：

10.1016/j.ultsonch.2017.09.039

中图分类号：

O42 [声学];

学科分类号：

070206 ; 082403 ;

摘要：

Submicron structures of N-II/Co-II-based coordination polymers (CPs) [Ni(L1)(mip)center dot H2O] (1) and {[Co(L2) (mip)]center dot 0.5H(2)O}(n) (2) (L1 = 1,6-bis(5,6-dimethylbenzimidazole)hexane, L2 = 1,6-bis(benzimidazole)hexane, H(2)mip = 5-methylisophthalic acid) were obtained by ultrasonic irradiation and structurally characterized by elemental analysis, powder X-ray diffraction and scanning electron microscopy. Structural analysis show that two CPs feature uninodal 3-connected 2D hcb layer, whilst CP 2 is further extended into a 3D complicated supramolecular network by C14-H14 center dot center dot center dot O-2 hydrogen bonds. Ultrasonic time and power influencing morphology of sub-micron sized CPs, were also discussed. Besides that, thermal stability, luminescence, electrochemical properties and photocatalytic activity of sub-micron sized 1 and 2 were presented in detail. Moreover, sub micron sized 1 manifests the higher photocatalytic activity than sub-micron sized 2 for decomposition of methylene blue (MB) under UV irradiation.

引用

页码：196 / 205

页数：10

共 77 条

[1] Sonochemical synthesis and characterization of microrod to nanoparticle of new mixed-ligand zinc(II) fumarate metal-organic polymer [J].