The ideal glass transition of hard spheres

被引:97
|
作者
Parisi, G
Zamponi, F
机构
[1] Univ Roma La Sapienza, Dipartimento Fis, I-00185 Rome, Italy
[2] Univ Roma La Sapienza, Ist Nazl Fis Nucl, SMC, CRS,INFM, I-00185 Rome, Italy
来源
JOURNAL OF CHEMICAL PHYSICS | 2005年 / 123卷 / 14期
关键词
D O I
10.1063/1.2041507
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We use the replica method to study the ideal glass transition of a liquid of identical hard spheres. We obtain estimates of the configurational entropy in the liquid phase, of the Kauzmann packing fraction phi(K), in the range of 0.58-0.62, and of the random close packing density phi(c), in the range of 0.64-0.67, depending on the approximation we use for the equation of state of the liquid. We also compute the pair-correlation function in the glassy states (i.e., dense amorphous packings) and we find that the mean coordination number at phi(c) is equal to 6. All these results compare well with numerical simulations and with other existing theories.
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页数:12
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