Possible contribution of triboelectricity to snow-air interactions

Reactions that proceed in polar snow cover may significantly affect the chemistry of the overlying atmosphere, but mechanisms and driving forces of these reactions are still under discussion. The proposed hypothesis attempts to explain some experimental data that cannot be fully understood (e. g. the effect of wind on OH radicals, ozone and persistent organic pollutants levels) by taking into account the influence of electrical phenomena on the snow surface. We assumed that a combination of such factors as low humidity, high wind speed and low temperatures makes the influence of triboelectrification of snow significant for polar areas, where purity and the depth of snow cover prevent fast charge dissipation. The major points of the hypothesis are: (1) when the electric field reaches a value sufficient for the onset of corona discharge, various free radical processes are initiated resulting in changes in the concentrations of ozone, OH radical, nitrate, etc., and the decomposition of pollutant molecules; (2) the high electric field can stimulate transport of ions (such as bromide and nitrate) from the condensed phase to the gas phase; and (3) the ageing of charged snow can increase its electrical potential.