Indium-Catalyzed Reductive Esterification of a Carboxylic Acid: Sequential Preparation of an Ester and Symmetrical Ether

被引：35

作者：

Sakai, Norio ^{[1
]}

Usui, Yuta ^{[1
]}

Ikeda, Reiko ^{[1
]}

Konakahara, Takeo ^{[1
]}

机构：

[1] Tokyo Univ Sci RIKADAI, Dept Pure & Appl Chem, Fac Sci & Technol, Noda, Chiba 2788510, Japan

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2011年 / 353卷 / 18期

关键词：

esterification; esters; etherification; ethers; indium; reduction; silanes; TISHCHENKO REACTION; EQUIMOLAR AMOUNTS; RUTHENIUM COMPLEXES; EFFICIENT CATALYST; NATURAL-PRODUCTS; SILYL ESTERS; ALCOHOLS; ALDEHYDES; CONVERSION; CONDENSATION;

D O I：

10.1002/adsc.201100524

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

An unprecedented reductive dimerization of two carboxylic acids to produce ester derivatives by a combination catalyst involving InBr3 and sulfuric acid is described. A sequential conversion of the in-situ formed ester to a symmetrical ether by indium-catalyzed deoxygenation of the ester with a hydrosilane in the same pot was also demonstrated.

引用

页码：3397 / 3401

页数：5

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