Ring expansions of 1-azabicyclo[n.1.0]alkanes. Recent developments

被引：6

作者：

Tymoshenko, Dmytro O. ^{[1
]}

机构：

[1] AMRI, 26 Corp Circle, Albany, NY 12203 USA

来源：

ARKIVOC | 2011年

关键词：

1-Azabicyclo[n.1.0]alkanes; ring expansion; aziridine; aziridinium; DIELS-ALDER REACTIONS; SUBSTITUTED; 3-FLUOROPIPERIDINES; ASYMMETRIC-SYNTHESIS; CONVENIENT ACCESS; RECEPTOR-BINDING; PIPERIDINES; GENERATION; PYRROLIDINES; DERIVATIVES; 2H-AZIRINES;

D O I：

10.3998/ark.5550190.0012.105

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the past decade ring expansion of aziridines and aziridiniums fused to other rings has developed into an attractive alternative method to classical pyrrolidine, piperidine and azepine ring construction approaches. This short review provides an update on recent reports and demonstrates the usefulness and the efficiency of this approach.

引用

页码：329 / 345

页数：17

共 57 条

[1] Formation of pyridin-4(1H)-one versus 1H-azepin-4(7H)-one by treatment of 4-tert-butyldimethylsilyloxy-2-amino-1-azabicyclo[4.1.0]hept-3-enes with tetrabutylammonium fluoride [J].