Properties and performance of silver-based catalysts on the catalytic oxidation of toluene

被引:16
作者
Kim, Sang Chai [1 ]
Ryu, Jae Yong [2 ]
机构
[1] Mokpo Natl Univ, Dept Environm Educ, Muan, Jeonnam, South Korea
[2] Korea Environm Ind & Technol Inst KEITI, R&D Planning & Support Off, Seoul, South Korea
关键词
catalytic oxidation; VOC; silver; catalyst; copper; VOLATILE ORGANIC-COMPOUNDS; ETHYLENE OXIDATION; OXIDE CATALYSTS; DEEP OXIDATION; CO OXIDATION; CERIA; HYDROCARBONS; INCINERATORS; COMBUSTION; MECHANISM;
D O I
10.1080/09593330.2010.505612
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Catalytic oxidation of volatile organic compounds such as toluene over a range of silver-based catalysts has been carried out to assess their performance. The properties of the catalysts were determined by the Brunauer-Emmett-Teller method, X-ray diffraction, and temperature-programmed reduction. The experimental results revealed that the catalytic activity of an Ag/-Al2O3 catalyst is closely related to the silver loading, and the optimum loading for the complete oxidation of toluene was found to be 11 wt%. The addition of copper to the 11 wt% Ag/-Al2O3 catalyst greatly enhanced its catalytic activity, but the addition of cerium or lanthanum inhibited catalytic activity.
引用
收藏
页码:561 / 568
页数:8
相关论文
共 38 条
[1]   Design of dual functional adsorbent/catalyst system for the control of VOC's by using metal-loaded hydrophobic Y-zeolites [J].
Baek, SW ;
Kim, JR ;
Ihm, SK .
CATALYSIS TODAY, 2004, 93-5 :575-581
[2]   AN UNUSUAL PROMOTION OF THE REDOX BEHAVIOR OF CEO2-ZRO2 SOLID-SOLUTIONS UPON SINTERING AT HIGH-TEMPERATURES [J].
BALDUCCI, G ;
FORNASIERO, P ;
DIMONTE, R ;
KASPAR, J ;
MERIANI, S ;
GRAZIANI, M .
CATALYSIS LETTERS, 1995, 33 (1-2) :193-200
[3]   Synthesis and characterisation of La1-xCaxFeO3 perovskite-type oxide catalysts for total oxidation of volatile organic compounds [J].
Barbero, Bibiana P. ;
Gamboa, Julio Andrade ;
Cadus, Luis E. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2006, 65 (1-2) :21-30
[4]   CO oxidation for the characterization of reducibility in oxygen storage components of three-way automotive catalysts [J].
Bunluesin, T ;
Gorte, RJ ;
Graham, GW .
APPLIED CATALYSIS B-ENVIRONMENTAL, 1997, 14 (1-2) :105-115
[5]  
CANT RB, 1987, J CHEM SOC F1, V83, P2035
[6]   CO, NO, and H-2 adsorption on ceria-supported Pd [J].
Cordatos, H ;
Gorte, RJ .
JOURNAL OF CATALYSIS, 1996, 159 (01) :112-118
[7]   Oxidation of volatile organic compounds on Al2O3, Pd/Al2O3, and PdO/Al2O3 catalysts [J].
Cordi, EM ;
Falconer, JL .
JOURNAL OF CATALYSIS, 1996, 162 (01) :104-117
[8]   Catalytic oxidation of volatile organic compounds (VOCs).: Oxidation of o-xylene over Pd and Pt/HFAU catalysts [J].
Dégé, P ;
Pinard, L ;
Magnoux, P ;
Guisnet, M .
COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE, 2001, 4 (01) :41-47
[9]   A NOVEL AND SIMPLE ROUTE TO CATALYSTS WITH A HIGH OXYGEN STORAGE CAPACITY - THE DIRECT ROOM-TEMPERATURE SYNTHESIS OF CEO2-ZRO2 SOLID-SOLUTIONS [J].
DELEITENBURG, C ;
TROVARELLI, A ;
ZAMAR, F ;
MASCHIO, S ;
DOLCETTI, G ;
LLORCA, J .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (21) :2181-2182
[10]  
DIWELL AF, 1991, CATALYSIS AUTOMOTIVE, V2, P139