Solid state precursor strategy for synthesizing hollow TiO2 boxes with a high percentage of reactive {001} facets exposed

被引:92
作者
Xie, Shuifen [1 ]
Han, Xiguang
Kuang, Qin
Fu, Jie
Zhang, Lei
Xie, Zhaoxiong
Zheng, Lansun
机构
[1] Xiamen Univ, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
基金
中国国家自然科学基金;
关键词
HIGH-INDEX FACETS; ANATASE TIO2; GOLD NANOCRYSTALS; TITANIA; NANOPARTICLES; NANOSHEETS;
D O I
10.1039/c1cc11542a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Three-dimensional, hollow, anatase TiO2 boxes, each was enclosed by six single-crystalline TiO2 plates exposed with highly reactive {001} facets, were facilely obtained by calcining a cubic TiOF2 solid precursor at 500-600 degrees C. The formation of such particular nanostructures is attributed to the hard self-template restriction and the adsorption of F- ions from the TiOF2.
引用
收藏
页码:6722 / 6724
页数:3
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