Manganese(III) corrole catalyzed selective oxidation of alcohols to carbonyl compounds by tert-butyl hydroperoxide under mild condition

被引：28

作者：

Bose, Suranjana ^{[1
]}

Pariyar, Anand ^{[1
]}

Biswas, Achintesh Narayan ^{[1
]}

Das, Purak ^{[1
]}

Bandyopadhyay, Pinaki ^{[1
]}

机构：

[1] Univ N Bengal, Dept Chem, Raja Rammohunpur 734013, Siliguri, India

来源：

CATALYSIS COMMUNICATIONS | 2011年 / 12卷 / 06期

关键词：

Manganese corrole; Catalysis; Alcohol oxidation; Tert-butyl hydroperoxide; METAL-COMPLEXES; METALLOCORROLES; EPOXIDATION; PYRROLE; OXYGEN; GREEN;

D O I：

10.1016/j.catcom.2010.10.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mild oxidation of alcohols has been achieved with tert-butylhydroperoxide catalyzed by electron deficient manganese(III) corroles at room temperature. The catalysts used in this study showed high activity in the oxidation of benzylic alcohols to the corresponding carbonyl compounds. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：446 / 449

页数：4

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