Microgel-stabilized metal nanoclusters: Size control by microgel nanomorphology

被引：139

作者：

Biffis, A ^{[1
]}

Orlandi, N ^{[1
]}

Corain, B ^{[1
]}

机构：

[1] Univ Padua, Dipartimento Chim Inorgan Metallorgan & Analit, I-35131 Padua, Italy

来源：

ADVANCED MATERIALS | 2003年 / 15卷 / 18期

关键词：

D O I：

10.1002/adma.200304977

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Soluble crosslinked macromolecules (micro-gels) used as stabilizers of catalytically active metal nanoclusters allow control of the nanocluster size by simply changing the crosslinking degree of the microgel. Microgel-stabilized metal nanoclusters are easily prepared and stored in the solid state, and those of Pd (see Figure) exhibit high catalytic activity in the Heck reaction of activated aryl bromides.

引用

页码：1551 / +

页数：6

共 29 条

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