Redetermination of (η4-s-cis-1,3-butadiene)tricarbonyliron(0)

被引：7

作者：

Reiss, Guido J. ^{[1
]}

机构：

[1] Univ Dusseldorf, Lehrstuhl Mat & Strukturforsch 2, Inst Anorgan Chem & Strukturchem, D-40225 Dusseldorf, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

COMPLEXES;

D O I：

10.1107/S1600536810039218

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of the title compound, [Fe(C4H6)(CO)(3)], was previously reported by Mills & Robinson [Acta Cryst. (1963), 16, 758-761]. The compound crystallizes in the centrosymmetric space goup Pnma with the complex located on a mirror plane. The redetermination of this structure at 100 K yielded almost equilibrated C-C bond lengths within the butadiene ligand according to a metal-to-ligand bonding-back-bonding mechanism. The C-C bond lengths presented herein are significantly shorter than those reported earlier. The H-atom positions that have not been reported so far were located by difference Fourier maps. The positional parameters of all H atoms and individual U-iso values were refined freely.

引用

页码：M1369 / U314

页数：7

共 13 条

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