Remote rearrangement of the metal center in a (η6-C6Me6)Ru(II) complex

被引：9

作者：

Takano, Koichi ^{[1
]}

Ikeda, Yousuke ^{[1
]}

Kodama, Shintaro ^{[1
]}

Ishii, Youichi ^{[1
]}

机构：

[1] Chuo Univ, Fac Sci & Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 112, Japan

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 24期

关键词：

C-H ACTIVATION; BOND ACTIVATION; 1,4-PALLADIUM MIGRATION; 1,4-METAL MIGRATION; EFFICIENT SYNTHESIS; ARYLZINC REAGENTS; RHODIUM; PALLADIUM; ALKYNES; ARYLATION;

D O I：

10.1039/c4cc09699a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of [(eta(6)-C6Me6)RuCl(Ph)(PMe3)] with internal alkynes in the presence of NaBAr4F gave rise to the 1,4-Ru migration to form the o-vinylaryl complex, providing the first example of 1,4-metal migration of a group 8 metal center; in one case further isomerization to an eta(3)-allyl complex was observed.

引用

页码：4981 / 4984

页数：4

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