Quantifying the "Subtle Interplay" between Intermolecular and Molecule-Substrate Interactions in Molecular Assembly on Surfaces

被引：16

作者：

White, Thomas W. ^{[1
]}

Martsinovich, Natalia ^{[2
]}

Troisi, Alessandro ^{[3
]}

Costantini, Giovanni ^{[1
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

[2] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

[3] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2018年 / 122卷 / 31期

基金：

英国工程与自然科学研究理事会; 欧洲研究理事会;

关键词：

LIQUID-SOLID INTERFACE; MM3; FORCE-FIELD; TEREPHTHALIC ACID; COORDINATION; NETWORKS; DEPROTONATION; ADSORPTION; MECHANICS; DYNAMICS; GRAPHENE;

D O I：

10.1021/acs.jpcc.8b06797

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effect of the concurrent action of intermolecular and molecule substrate interactions on the two-dimensional (2D) self-assembly of organic molecules on solid surfaces is investigated in a combined experimental and theoretical effort. Scanning tunneling microscopy measurements of terephthalic acid on the Cu(111) surface, a model system where the interplay between the two interactions is particularly evident, are used to develop a general, simple, and computationally inexpensive model that quantitatively accounts for the experimental observations. The model, related to the well-known Frenkel-Kontorova model, offers a comprehensive description of the "subtle interplay" between intermolecular and molecule-substrate interactions and provides a qualitative and quantitative predictive capability in the design and fabrication of 2D molecular nanostructures at surfaces.

引用

页码：17954 / 17962

页数：17

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