Quantifying the "Subtle Interplay" between Intermolecular and Molecule-Substrate Interactions in Molecular Assembly on Surfaces

被引：16

作者：

White, Thomas W. ^{[1
]}

Martsinovich, Natalia ^{[2
]}

Troisi, Alessandro ^{[3
]}

Costantini, Giovanni ^{[1
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

[2] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

[3] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2018年 / 122卷 / 31期

基金：

英国工程与自然科学研究理事会; 欧洲研究理事会;

关键词：

LIQUID-SOLID INTERFACE; MM3; FORCE-FIELD; TEREPHTHALIC ACID; COORDINATION; NETWORKS; DEPROTONATION; ADSORPTION; MECHANICS; DYNAMICS; GRAPHENE;

D O I：

10.1021/acs.jpcc.8b06797

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effect of the concurrent action of intermolecular and molecule substrate interactions on the two-dimensional (2D) self-assembly of organic molecules on solid surfaces is investigated in a combined experimental and theoretical effort. Scanning tunneling microscopy measurements of terephthalic acid on the Cu(111) surface, a model system where the interplay between the two interactions is particularly evident, are used to develop a general, simple, and computationally inexpensive model that quantitatively accounts for the experimental observations. The model, related to the well-known Frenkel-Kontorova model, offers a comprehensive description of the "subtle interplay" between intermolecular and molecule-substrate interactions and provides a qualitative and quantitative predictive capability in the design and fabrication of 2D molecular nanostructures at surfaces.

引用

页码：17954 / 17962

页数：17

共 65 条

[1] Defects and Domain Boundaries in Self-Assembled Terephthalic Acid (TPA) Mono layers on CVD-Grown Graphene on Pt(111)
Addou, Rafik
Batzill, Matthias
[J]. LANGMUIR, 2013, 29 (21) : 6354 - 6360
[2] MOLECULAR MECHANICS - THE MM3 FORCE-FIELD FOR HYDROCARBONS .1.
ALLINGER, NL
YUH, YH
LII, JH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (23) : 8551 - 8566
[3] CRYSTAL STRUCTURE OF TEREPHTHALIC ACID
BAILEY, M
BROWN, CJ
[J]. ACTA CRYSTALLOGRAPHICA, 1967, 22 : 387 - &
[4] Bartels L, 2010, NAT CHEM, V2, P87, DOI [10.1038/NCHEM.517, 10.1038/nchem.517]
[5] Fresh perspectives for surface coordination chemistry
Barth, Johannes V.
[J]. SURFACE SCIENCE, 2009, 603 (10-12) : 1533 - 1541
[6] Systematics of Molecular Self-Assembled Networks at Topological Insulators Surfaces
Bathon, T.
Sessi, P.
Kokh, K. A.
Tereshchenko, O. E.
Bode, M.
[J]. NANO LETTERS, 2015, 15 (04) : 2442 - 2447
[7] Rings sliding on a honeycomb network: Adsorption contours, interactions, and assembly of benzene on Cu(111)
Berland, K.
Einstein, T. L.
Hyldgaard, P.
[J]. PHYSICAL REVIEW B, 2009, 80 (15)
[8] Adsorption and two-dimensional phases of a large polar molecule:: Sub-phthalocyanine on Ag(111) -: art. no. 115410
Berner, S
de Wild, M
Ramoino, L
Ivan, S
Baratoff, A
Güntherodt, HJ
Suzuki, H
Schlettwein, D
Jung, TA
[J]. PHYSICAL REVIEW B, 2003, 68 (11)
[9] Inhomogeneous Relaxation of a Molecular Layer on an Insulator due to Compressive Stress
Bocquet, F.
Nony, L.
Mannsfeld, S. C. B.
Oison, V.
Pawlak, R.
Porte, L.
Loppacher, Ch.
[J]. PHYSICAL REVIEW LETTERS, 2012, 108 (20)
[10] CALCULATION OF SMALL MOLECULAR INTERACTIONS BY DIFFERENCES OF SEPARATE TOTAL ENERGIES - SOME PROCEDURES WITH REDUCED ERRORS
BOYS, SF
BERNARDI, F
[J]. MOLECULAR PHYSICS, 1970, 19 (04) : 553 - &

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