Synthesis and Characterization of Allyl Terpene Maleate Monomer

被引:1
|
作者
Gu, Yan [1 ,2 ]
Hummel, Matthew [2 ]
Muthukumarappan, Kasiviswanathan [2 ]
Zhao, Zhendong [1 ]
Gu, Zhengrong [2 ]
机构
[1] Natl Forestry & Grassland Adm, Key Lab Biomass Energy & Mat, Key Lab Chem Engn Forest Prod, Natl Engn Lab Biomass Chem Utilizat,CAF,Inst Chem, Nanjing 210042, Jiangsu, Peoples R China
[2] South Dakota State Univ, Agr & Biosyst Engn Dept, Brookings, SD 57006 USA
基金
美国食品与农业研究所;
关键词
POLYESTERS;
D O I
10.1038/s41598-019-55356-8
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Terpenes and their derivatives are sustainable, renewable chemicals that can be used as a complementary hydrocarbon. The exceptions are fossil-based feedstocks and lignin-based feedstocks. A simple method has been found to prepare allyl terpene maleate monomer by substitution reaction at lower reaction temperatures. Using terpenes from turpentine, maleic anhydride and allyl chloride as reactants, the synthesized monomer, terpene-diallyl maleate adduct, was prepared by D-A addition, hydrolysis, and substitution reaction. The resultant monomer was characterized for the first time. The synthesized product will be a versatile monomer and a very important intermediate, having broad application prospects. The synthesized monomer will replace similar aromatic compounds in certain applications because of its low-toxicity and sustainability. The synthesized monomer with two terminal olefin structures has great free radical polymerization potential, according to its physical and chemical properties and exploratory experimentation.
引用
收藏
页数:11
相关论文
共 50 条
  • [31] SYNTHESIS AND CHARACTERIZATION OF POLYESTERS FROM RENEWABLE CARDOL
    Makame, Y. M. M.
    Mubofu, E. B.
    Kombo, M. A.
    BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA, 2016, 30 (02) : 273 - 282
  • [32] Synthesis and characterization of polyesters based on diethylketone moiety
    Ismail A. Alkskas
    Bashir A. El-gnidi
    Khadija M. Ghalieo
    Faizul Azam
    Chinese Journal of Polymer Science, 2014, 32 : 1450 - 1459
  • [33] Synthesis and characterization of unsaturated polyester/carborundum composites
    Asaad, Jeannette N.
    JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 129 (04) : 1812 - 1819
  • [34] SYNTHESIS AND CHARACTERIZATION OF A FLAME RETARDANT HYPERBRANCHED POLYETHER
    Borah, Jyotishmoy
    Wang, Chuan-sheng
    Karak, Niranjan
    CHINESE JOURNAL OF POLYMER SCIENCE, 2010, 28 (01) : 107 - 118
  • [35] Synthesis and characterization of azoxy based mesogenic diols
    Mulani, Khudbudin B.
    Ganjave, Nitin V.
    Chavan, Nayaku N.
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2014, 53 (03): : 359 - 362
  • [36] Synthesis and characterization of polyesters based on diethylketone moiety
    Alkskas, Ismail A.
    El-gnidi, Bashir A.
    Ghalieo, Khadija M.
    Azam, Faizul
    CHINESE JOURNAL OF POLYMER SCIENCE, 2014, 32 (11) : 1450 - 1459
  • [37] Synthesis and characterization of natural fibre with ZnO nanocomposites
    Y. Brucely
    Y. Christabel Shaji
    G. Paulraj
    D. Manikandan
    N. Nagaprasad
    Rajesh Singh
    Lovi Raj Gupta
    Jule Leta Tesfaye
    Bayissa Badassa
    R. Krishnaraj
    International Journal on Interactive Design and Manufacturing (IJIDeM), 2023, 17 : 2445 - 2452
  • [38] Synthesis, characterization and in vitro antimicrobial and biodegradability study of pseudo-poly(amino acid)s derived from N,N'-(pyromellitoyl)-bis-l-tyrosine dimethyl ester as a chiral bioactive diphenolic monomer
    Mallakpour, Shadpour
    Tirgir, Farhang
    Sabzalian, Mohammad R.
    AMINO ACIDS, 2011, 40 (02) : 611 - 621
  • [39] Synthesis and properties of allyl terminated renewable non-isocyanate polyurethanes (NIPUs) and polyureas (NIPUreas) and study of their photo-crosslinking
    Martin, Amelie
    Lecamp, Laurence
    Labib, Hager
    Aloui, Faten
    Kebir, Nasreddine
    Burel, Fabrice
    EUROPEAN POLYMER JOURNAL, 2016, 84 : 828 - 836
  • [40] Lipase-catalyzed synthesis of biobased and biodegradable aliphatic copolyesters from short building blocks. Effect of the monomer length
    Debuissy, Thibaud
    Pollet, Eric
    Averous, Luc
    EUROPEAN POLYMER JOURNAL, 2017, 97 : 328 - 337