Point-and-Shoot Strategy for Identification of Alcoholic Beverages

被引:15
作者
Li, Zelun [1 ]
Chang, Xuling [2 ]
Wang, Ying [1 ]
Wei, Changting [1 ]
Wang, Juan [1 ]
Ai, Kelong [1 ]
Zhang, Ye [2 ]
Lu, Lehui [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, 5625 Renmin St, Changchun 130022, Peoples R China
[2] Chinese Acad Sci, Changchun Inst Opt Fine Mech & Phys, State Key Lab Appl Opt, Changchun 130033, Jilin, Peoples R China
基金
中国国家自然科学基金;
关键词
SEMICONDUCTING POLYMER DOTS; CONJUGATED POLYMER; POLYDIACETYLENES; DIFFERENTIATION; CONSTRUCTION; RECOGNITION; ALIGNMENT; CARBON; PHASE; ARRAY;
D O I
10.1021/acs.analchem.8b01895
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The lack of point-and-shoot detection methods of alcoholic beverages (ABs) available for ordinary people is a common cause of the overflow of various counterfeit ABs. Here, we, for the first time, provide a point-and-shoot identification for ABs via a smartphone. Using density functional theory, we find the binding ability of an ethylenediamine-functionalized polydiacetylene (P4) can reach a desirable trade-off among organic molecules in ABs. We therefore construct a versatile array consisting of P4 with different concentrations, which is able to generate unique color response patterns toward different ABs. The color response patterns are further analyzed by a custom-designed image processing algorithm based on machine learning. Finally, the identification of ABs can be achieved by capturing and analyzing the color pattern using an imaging recognition programmer on a smartphone, and the entire process is as fast as quick response (QR) code scanning. Our point-and-shoot strategy makes the identification of ABs accessible to every mobile phone user.
引用
收藏
页码:9838 / 9844
页数:7
相关论文
共 51 条
[1]   Fluorogenic polydiacetylene supramolecules: Immobilization, micropatterning, and application to label-free chemosensors [J].
Ahn, Dong June ;
Kim, Jong-Man .
ACCOUNTS OF CHEMICAL RESEARCH, 2008, 41 (07) :805-816
[2]   SELF-ASSEMBLED MONOLAYERS CONTAINING POLYDIACETYLENES [J].
BATCHELDER, DN ;
EVANS, SD ;
FREEMAN, TL ;
HAUSSLING, L ;
RINGSDORF, H ;
WOLF, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (03) :1050-1053
[3]   TOTAL ALIGNMENT OF CALCITE AT ACIDIC POLYDIACETYLENE FILMS - COOPERATIVITY AT THE ORGANIC-INORGANIC INTERFACE [J].
BERMAN, A ;
AHN, DJ ;
LIO, A ;
SALMERON, M ;
REICHERT, A ;
CHARYCH, D .
SCIENCE, 1995, 269 (5223) :515-518
[4]   Smartphone-based blood pressure monitoring via the oscillometric finger-pressing method [J].
Chandrasekhar, Anand ;
Kim, Chang-Sei ;
Naji, Mohammed ;
Natarajan, Keerthana ;
Hahn, Jin-Oh ;
Mukkamala, Ramakrishna .
SCIENCE TRANSLATIONAL MEDICINE, 2018, 10 (431)
[5]   DIRECT COLORIMETRIC DETECTION OF A RECEPTOR-LIGAND INTERACTION BY A POLYMERIZED BILAYER ASSEMBLY [J].
CHARYCH, DH ;
NAGY, JO ;
SPEVAK, W ;
BEDNARSKI, MD .
SCIENCE, 1993, 261 (5121) :585-588
[6]   Thin-Film Formation of Imidazolium-Based Conjugated Polydiacetylenes and Their Application for Sensing Anionic Surfactants [J].
Chen, Xiaoqiang ;
Kang, Sunwoo ;
Kim, Min Jung ;
Kim, Joohee ;
Kim, Youn Sang ;
Kim, Heejin ;
Chi, Bo ;
Kim, Sung-Jin ;
Lee, Jin Yong ;
Yoon, Juyoung .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (08) :1422-1425
[7]   AN ALL-ELECTRON NUMERICAL-METHOD FOR SOLVING THE LOCAL DENSITY FUNCTIONAL FOR POLYATOMIC-MOLECULES [J].
DELLEY, B .
JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (01) :508-517
[8]   From molecules to solids with the DMol3 approach [J].
Delley, B .
JOURNAL OF CHEMICAL PHYSICS, 2000, 113 (18) :7756-7764
[9]   Synthesis and Alignment of Discrete Polydiacetylene-Peptide Nanostructures [J].
Diegelmann, Stephen R. ;
Hartman, Nikolaus ;
Markovic, Nina ;
Tovar, John D. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (04) :2028-2031
[10]   Nature's Chemical Signatures in Human Olfaction: A Foodborne Perspective for Future Biotechnology [J].
Dunkel, Andreas ;
Steinhaus, Martin ;
Kotthoff, Matthias ;
Nowak, Bettina ;
Krautwurst, Dietmar ;
Schieberle, Peter ;
Hofmann, Thomas .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (28) :7124-7143