Solubilities, vapor pressures, densities, and viscosities of the (water plus lithium bromide plus lithium iodide plus lithium chloride) system

被引:11
作者
Koo, KK
Lee, HR
Jeong, S
Oh, YS
Park, DR
Baek, YS
机构
[1] Sogang Univ, Dept Chem Engn, Seoul 100611, South Korea
[2] Sogang Univ, Dept Engn Mech, Seoul 100611, South Korea
[3] Korea Gas Corp, R&D Ctr, Ansan 425150, South Korea
关键词
D O I
10.1021/je980063l
中图分类号
O414.1 [热力学];
学科分类号
摘要
Measurements of thermophysical properties of the (water + lithium bromide + lithium iodide + lithium chloride) system (LiBr:LiI:LiCl = 4.5:1:2 by mole ratio) were performed as functions of concentration and temperature. Solubilities were measured by a visual polythermal method at temperatures from (248.59 to 350.46) K. Regression equations were obtained with a least-squares method, and the average absolute deviations of the calculated values from the experimental data were 0.10% (solution temperature 284.59 K) and 0.12% (temperature > 284.59 K), respectively. The vapor pressures were measured by a boiling point method at lithium salts concentrations from (50.0 to 70.0) mass % and temperatures from (318.36 to 455.75) K. The experimental data were correlated with an Antoine-type equation. The average absolute deviation of the calculated values from the experimental data was 1.83%. Densities and viscosities were measured at concentrations from (50.0 to 64.0) mass % and temperatures from (283.15 to 333.15) K. Regression equations for densities and viscosities were obtained with a least-squares method, and the average absolute deviations of the calculated values from the experimental data were 0.08% and 0.87%, respectively.
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页码:722 / 725
页数:4
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