Alkane-length sorting using activated pillar[5]arene crystals

被引:49
作者
Ogoshi, Tomoki [1 ,2 ]
Sueto, Ryuta [1 ]
Hamada, Yukie [1 ]
Doitomi, Kazuki [3 ]
Hirao, Hajime [2 ,3 ,4 ]
Sakata, Yoko [1 ]
Akine, Shigehisa [1 ]
Kakuta, Takahiro [1 ]
Yamagishi, Tada-aki [1 ]
机构
[1] Kanazawa Univ, Grad Sch Nat Sci & Technol, Kakuma Machi, Kanazawa, Ishikawa 9201192, Japan
[2] Japan Sci & Technol Agcy JST, PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama 3320012, Japan
[3] City Univ Hong Kong, Dept Biol & Chem, Tat Chee Ave, Kowloon, Hong Kong, Peoples R China
[4] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, 21 Nanyang Link, Singapore 637371, Singapore
关键词
HOST-GUEST COMPLEXATION; SUPRAMOLECULAR CHEMISTRY; ORGANIC FRAMEWORKS; N-ALKANES; COMPASS;
D O I
10.1039/c7cc04454b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report a simple and easy-to-operate method for separating n-alkanes: when we immersed activated pillar[5] arene crystals into a mixture of n-alkanes with various chain lengths, the crystals preferentially took up n-alkanes with longer chain lengths.
引用
收藏
页码:8577 / 8580
页数:4
相关论文
共 22 条
[1]   More Chemistry in Small Spaces [J].
Ajami, Dariush ;
Rebek, Julius, Jr. .
ACCOUNTS OF CHEMICAL RESEARCH, 2013, 46 (04) :990-999
[2]  
[Anonymous], 2015, BIOVIA MAT STUDIO 8
[3]   Selective Adsorption of n-Alkanes from n-Octane on Metal-Organic Frameworks: Length Selectivity [J].
Bhadra, Biswa Nath ;
Jhung, Sung Hwa .
ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (10) :6770-6777
[4]   Pillar[5]arenes: fascinating cyclophanes with a bright future [J].
Cragg, Peter J. ;
Sharma, Kushal .
CHEMICAL SOCIETY REVIEWS, 2012, 41 (02) :597-607
[5]   Novel cavity design using calix[n]arene skeletons: Toward molecular recognition and metal binding [J].
Ikeda, A ;
Shinkai, S .
CHEMICAL REVIEWS, 1997, 97 (05) :1713-1734
[6]   Cucurbituril homologues and derivatives: New opportunities in supramolecular chemistry [J].
Lee, JW ;
Samal, S ;
Selvapalam, N ;
Kim, HJ ;
Kim, K .
ACCOUNTS OF CHEMICAL RESEARCH, 2003, 36 (08) :621-630
[7]   para-bridged symmetrical pillar[5]arenes:: Their Lewis acid catalyzed synthesis and host-guest property [J].
Ogoshi, Tomoki ;
Kanai, Suguru ;
Fujinami, Shuhei ;
Yamagishi, Tada-aki ;
Nakamoto, Yoshiaki .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (15) :5022-5023
[8]   Pillar-Shaped Macrocyclic Hosts Pillar[n]arenes: New Key Players for Supramolecular Chemistry [J].
Ogoshi, Tomoki ;
Yamagishi, Tada-aki ;
Nakamoto, Yoshiaki .
CHEMICAL REVIEWS, 2016, 116 (14) :7937-8002
[9]   Host-Guest Complexation of Perethylated Pillar[5]arene with Alkanes in the Crystal State [J].
Ogoshi, Tomoki ;
Sueto, Ryuta ;
Yoshikoshi, Kumiko ;
Sakata, Yoko ;
Akine, Shigehisa ;
Yamagishi, Tada-aki .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (34) :9849-9852
[10]   Cyclic Host Liquids for Facile and High-Yield Synthesis of [2]Rotaxanes [J].
Ogoshi, Tomoki ;
Aoki, Takamichi ;
Shiga, Ryohei ;
Iizuka, Ryo ;
Ueda, Seita ;
Demachi, Kazuki ;
Yamafuji, Daiki ;
Kayama, Hitoshi ;
Yamagishi, Tada-aki .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (50) :20322-20325