A New Mo(VI) Complex of (E)-2-(((5-hydroxypentyl)imino)methyl)-6-methoxyphenol: Synthesis, Characterization, and X-Ray Crystal Structure

被引：3

作者：

Sheikhshoaie, Iran ^{[1
]}

Ebrahimipour, S. Yousef ^{[1
]}

Shamsi, Somayeh ^{[1
]}

机构：

[1] Shahid Bahonar Univ Kerman, Dept Chem, Fac Sci, Kerman 76175133, Iran

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2016年 / 46卷 / 06期

关键词：

Schiff base ligand; Mo(VI) complex; ONO donor; crystal structure; spectroscopic characterization; CATALYTIC-ACTIVITY; DFT CALCULATION; NLO BEHAVIOR; BASE; COPPER(II); NMR;

D O I：

10.1080/15533174.2014.989612

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A tridentate ONO Schiff base ligand, (E)-2-(((5-hydroxypentyl)imino)methyl)-6-methoxyphenol [H2L], and its Mo(VI) complex [MoL], have been synthesized and structurally characterized by elemental analysis, FT-IR, NMR, and UV-Vis spectroscopy. The structure of the Mo(VI) complex has been determined by single-crystal X-ray diffraction. This complex has octahedral geometry around central atom. Yellow crystals crystallize in orthorhombic, space group Pbca with a = 17.8718(10) angstrom, b = 17.4516(10) angstrom, c, 18.1872(10) angstrom and alpha = beta = gamma = 90 degrees.

引用

页码：917 / 921

页数：5

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