A Family of Homo- and Heteroscorpionate Ligands: Applications to Bioinorganic Chemistry

被引：21
|
作者：
Carrano, Carl J. [1 ]
机构：
[1] San Diego State Univ, Dept Chem & Biochem, San Diego, CA 92182 USA
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2016年 / 15-16期
基金：
美国国家科学基金会;
关键词：
Bioinorganic chemistry; Metalloenzyme mimics; Scorpionate ligands; Heteroscorpionate ligands; Molybdenum; Zinc; DIMETHYL-SULFOXIDE REDUCTASE; RELEVANT SCORPIONATE LIGANDS; (2-METHYLETHANETHIOL-BIS-3,5-DIMETHYLPYRAZOLYL)METHANE ZINC-COMPLEXES; MONONUCLEAR OXO-MOLYBDENUM(V) COMPLEXES; ATOM-TRANSFER-REACTIONS; CRYSTAL-STRUCTURE; ESCHERICHIA-COLI; STRUCTURAL-CHARACTERIZATION; DMSO REDUCTASE; ALKYL TRANSFER;
D O I：
10.1002/ejic.201501476
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In this brief review we focus on a few examples of how a family of homo- and heteroscorpionate ligands allow us to examine how changes in reactivity, structure, or physical/chemical properties around biologically interesting N2X coordinated metal centers vary as a function of donor atom, charge, hydrophobicity, hydrogen bonding, etc., in a way previously unavailable. Such a family of ligands is the bioinorganic chemists answer to site-directed mutagenesis. Here we focus on two bioinorganic examples i.e. models for molybdoenzymes and zinc metalloproteins.
引用
收藏
页码：2377 / 2390
页数：14
相关论文
共 37 条
  • [1] Non-innocent ligands in bioinorganic chemistry-An overview
    Kaim, Wolfgang
    Schwederski, Brigitte
    COORDINATION CHEMISTRY REVIEWS, 2010, 254 (13-14) : 1580 - 1588
  • [2] Facile Access to Homo- and Heteroleptic, Triply Bonded Dimolybdenum Hexaalkoxides with Unsaturated Alkoxide Ligands
    Krackl, Sebastian
    Ma, Jian-Gong
    Aksu, Yilmaz
    Driess, Matthias
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2011, (11) : 1725 - 1732
  • [3] Oxidative coupling reactions at ruthenium(0) and their applications to catalytic homo- and cross-dimerizations
    Hirano, Masafumi
    Komiya, Sanshiro
    COORDINATION CHEMISTRY REVIEWS, 2016, 314 : 182 - 200
  • [4] Metal complexes with heteroscorpionate ligands based on the bis(pyrazol-1-yl)methane moiety: Catalytic chemistry
    Otero, Antonio
    Fernandez-Baeza, Juan
    Lara-Sanchez, Agustin
    Sanchez-Barba, Luis F.
    COORDINATION CHEMISTRY REVIEWS, 2013, 257 (11-12) : 1806 - 1868
  • [5] Homo- and Hetero-Oligonuclear Complexes of Platinum Group Metals (PGM) Coordinated by Imine Schiff Base Ligands
    Miroslaw, Barbara
    INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2020, 21 (10)
  • [6] Homo- and heteroduplex complexes containing terpyridine-type ligands and Zn2+
    Dumitru, F
    Petit, E
    van der Lee, A
    Barboiu, M
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (21) : 4255 - 4262
  • [7] An overview of the chemistry of homo and heteropolynuclear platinum complexes containing bridging acetylide (μ-CCR) ligands
    Berenguer, Jesus R.
    Lalinde, Elena
    Teresa Moreno, M.
    COORDINATION CHEMISTRY REVIEWS, 2010, 254 (7-8) : 832 - 875
  • [8] Synthesis of Homo- and Heteroleptic Al, Ga and Zn Complexes Containing (Per)fluorinated β-Diketiminate Ligands
    Huse, Kevin
    Li, Bin
    Ghosh, Swarup
    Woelper, Christoph
    Schulz, Stephan
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2021, 647 (05): : 430 - 435
  • [9] Coordination and bioinorganic chemistry of aryl-appended tris(2-pyridylmethyl) amine ligands
    Berreau, Lisa M.
    COMMENTS ON INORGANIC CHEMISTRY, 2007, 28 (3-4) : 123 - 171
  • [10] Synthesis and Characterization of 3d-3d Homo- and Heterometallic Coordination Polymers with Mixed Ligands
    Su, Zhi
    Bai, Zheng-Shuai
    Fan, Jian
    Xu, Jing
    Sun, Wei-Yin
    CRYSTAL GROWTH & DESIGN, 2009, 9 (12) : 5190 - 5196
1234