Selective hydrogenation of nitroarenes using an electrogenerated polyoxometalate redox mediator

被引：49

作者：

MacDonald, Lewis ^{[1
]}

Rausch, Benjamin ^{[1
]}

Symes, Mark D. ^{[1
]}

Cronin, Leroy ^{[1
]}

机构：

[1] Univ Glasgow, Sch Chem, WestCHEM, Univ Ave, Glasgow G12 8QQ, Lanark, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 09期

基金：

英国工程与自然科学研究理事会; 欧洲研究理事会;

关键词：

COUPLED-PROTON BUFFER; AROMATIC-AMINES; WATER; REDUCTION; EVOLUTION; ACID; SLUDGE;

D O I：

10.1039/c7cc09036f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 2-electron reduced form of the polyoxometalate silicotungstic acid (H-4[SiW12O4]) is shown to be an effective and selective hydrogenation agent for a range of nitroarenes without the need for any co-catalyst. The ease of generation of the active species and its recyclability suggest that a new approach to this important class of chemical conversions is possible.

引用

页码：1093 / 1096

页数：4

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