Excess electron transfer dynamics in DNA hairpins conjugated with N,N-dimethylaminopyrene as a photosensitizing electron donor

被引：9

作者：

Park, Man Jae ^{[1
]}

Fujitsuka, Mamoru ^{[1
]}

Nishitera, Haruhiro ^{[1
]}

Kawai, Kiyohiko ^{[1
]}

Majima, Tetsuro ^{[1
]}

机构：

[1] Osaka Univ, Inst Sci & Ind Res SANKEN, Ibaraki, Osaka 5670047, Japan

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 89期

基金：

新加坡国家研究基金会;

关键词：

HOLE-TRANSFER; TRANSPORT; NUCLEOBASE; DEPENDENCE; SEQUENCE; BASES;

D O I：

10.1039/c2cc36054c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Excess electron transfer dynamics in DNA hairpins was investigated by femtosecond laser flash photolysis of a donor-DNA-acceptor system using N,N-dimethylaminopyrene and diphenylacetylene as an electron donor and acceptor, respectively. It was revealed that the excess electron hopping rate between T's is faster than that of the hole.

引用

页码：11008 / 11010

页数：3

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