A ruthenium-based catalyst system for hydrovinylation at room temperature

被引：23

作者：

Sanchez, Richard P., Jr. ^{[1
]}

Connell, Brian T. ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 13期

关键词：

D O I：

10.1021/om8002784

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A catalytic amount of RuHCl(CO)(PCy(3))(2) (1) activated with AgOTF or AgSbF(6) at room temperature was found to be an effective catalyst system for the hydrovinylation of vinylarenes. Vinylarenes with both electron-donating and electron-withdrawing substituents reacted with ethylene at room temperature to provide the desired 3-arylbutenes in moderate to excellent yield (60-99%) under mild reaction conditions.

引用

页码：2902 / 2904

页数：3

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