ECS-3: A Crystalline Hybrid Organic-Inorganic Aluminosilicate with Open Porosity

被引：53
作者：
Bellussi, Giuseppe [1 ]
Montanari, Erica [1 ]
Di Paola, Eleonora [1 ]
Millini, Roberto [1 ]
Carati, Angela [1 ]
Rizzo, Caterina [1 ]
Parker, Wallace O'Neil, Jr. [1 ]
Gemmi, Mauro [2 ,3 ]
Mugnaioli, Enrico [4 ]
Kolb, Ute [4 ]
Zanardi, Stefano [1 ]
机构：
[1] Eni Spa Refining & Mkt Div, I-20097 San Donato Milanese, Italy
[2] Univ Milan, Dipartimento Sci Terra A Desio, I-20133 Milan, Italy
[3] Ctr Nanotechnol Innovat NEST Ist Italiano Tecnol, Pisa, Italy
[4] Johannes Gutenberg Univ Mainz, Inst Phys Chem, D-55099 Mainz, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 03期
关键词：
electron diffraction; hydrothermal synthesis; organic-inorganic hybrid composites; structure elucidation; zeolite analogues; AUTOMATED DIFFRACTION TOMOGRAPHY; ZEOLITE;
D O I：
10.1002/anie.201105496
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Automated diffraction tomography was used to collect electron-diffraction data for solving the crystal structure of ECS-3, which is the first example of a crystalline hybrid organic-inorganic aluminosilicate with open porosity, generated by a regular arrangement of phenylene rings interconnecting aluminosilicate layers (see picture; Al turquoise, C gray, O red, Si gold). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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页码：666 / 669
页数：4
相关论文
共 24 条
[1]   Structure analysis of titanate nanorods by automated electron diffraction tomography [J].
Andrusenko, Iryna ;
Mugnaioli, Enrico ;
Gorelik, Tatiana E. ;
Koll, Dominik ;
Panthoefer, Martin ;
Tremel, Wolfgang ;
Kolb, Ute .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2011, 67 :218-225
[2]   Ordered silicon vacancies in the framework structure of the zeolite catalyst SSZ-74 [J].
Baerlocher, Christian ;
Xie, Dan ;
McCusker, Lynne B. ;
Hwang, Son-Jong ;
Chan, Ignatius Y. ;
Ong, Kenneth ;
Burton, Allen W. ;
Zones, Stacey I. .
NATURE MATERIALS, 2008, 7 (08) :631-635
[3]   Structure of the polycrystalline zeolite catalyst IM-5 solved by enhanced charge flipping [J].
Baerlocher, Christian ;
Gramm, Fabian ;
Massueger, Lars ;
McCusker, Lynne B. ;
He, Zhanbing ;
Hovmoeller, Sven ;
Zou, Xiaodong .
SCIENCE, 2007, 315 (5815) :1113-1116
[4]   Crystalline hybrid organic-inorganic alumino-silicates [J].
Bellussi, Giuseppe ;
Carati, Angela ;
Di Paola, Eleonora ;
Millini, Roberto ;
Parker, Wallace O'Neil, Jr. ;
Rizzo, Caterina ;
Zanardi, Stefano .
MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 113 (1-3) :252-260
[5]   Solution Synthesis of a New Thermoelectric Zn1-xSb Nanophase and Its Structure Determination Using Automated Electron Diffraction Tomography [J].
Birkel, Christina S. ;
Mugnaioli, Enrico ;
Gorelik, Tatiana ;
Kolb, Ute ;
Panthoefer, Martin ;
Tremel, Wolfgang .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (28) :9881-9889
[6]   SIR2004:: an improved tool for crystal structure determination and refinement [J].
Burla, MC ;
Caliandro, R ;
Camalli, M ;
Carrozzini, B ;
Cascarano, GL ;
De Caro, L ;
Giacovazzo, C ;
Polidori, G ;
Spagna, R .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2005, 38 :381-388
[7]  
Ceika J., 2007, INTRO ZEOLITE SCI PR
[8]   A zeolite with interconnected 8-, 10- and 12-ring pores and its unique catalytic selectivity [J].
Corma, A ;
Rey, F ;
Valencia, S ;
Jordá, JL ;
Rius, J .
NATURE MATERIALS, 2003, 2 (07) :493-497
[9]   NEW RHODIUM COMPLEXES ANCHORED ON MODIFIED USY ZEOLITES - A REMARKABLE EFFECT OF THE SUPPORT ON THE ENANTIOSELECTIVITY OF CATALYTIC-HYDROGENATION OF PROCHIRAL ALKENES [J].
CORMA, A ;
IGLESIAS, M ;
DELPINO, C ;
SANCHEZ, F .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (18) :1253-1255
[10]   Elucidating Gating Effects for Hydrogen Sorption in MFU-4-Type Triazolate-Based Metal-Organic Frameworks Featuring Different Pore Sizes [J].
Denysenko, Dmytro ;
Grzywa, Maciej ;
Tonigold, Markus ;
Streppel, Barbara ;
Krkljus, Ivana ;
Hirscher, Michael ;
Mugnaioli, Enrico ;
Kolb, Ute ;
Hanss, Jan ;
Volkmer, Dirk .
CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (06) :1837-1848
123