Solvothermal alcoholysis synthesis of hierarchical TiO2 with enhanced activity in environmental and energy photocatalysis

被引：85

作者：

Bian, Zhenfeng ^{[1
,2
]}

Zhu, Jian ^{[1
,2
]}

Li, Hexing ^{[3
]}

机构：

[1] Shanghai Normal Univ, Educ Minist, Key Lab Resource Chem, Shanghai 200234, Peoples R China

[2] Shanghai Normal Univ, Shanghai Key Lab Rare Earth Funct Mat, Shanghai 200234, Peoples R China

[3] Shanghai Univ Elect Power, Coll Environm & Chem Engn, Shanghai 201300, Peoples R China

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS | 2016年 / 28卷

关键词：

Solvothermal alcoholysis; Titanium dioxide; Structure control; Environmental and energy; Photocatalysis; Hierarchical structure; SENSITIZED SOLAR-CELLS; VISIBLE-LIGHT-DRIVEN; EXPOSED; 001; FACETS; MESOPOROUS TIO2; ANATASE TIO2; NONAQUEOUS SYNTHESIS; TITANIUM-DIOXIDE; NANOCRYSTALLINE TIO2; CATALYTIC PERFORMANCE; SELECTIVE OXIDATION;

D O I：

10.1016/j.jphotochemrev.2016.06.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Titanium dioxide (TiO2) represents the most widely used semiconductor photocatalysts and photovoltaics owing to its stability, low cost, and nontoxicity properties. The performances of TiO2 highly governed by the physical and chemical properties such as specific surface area, particle size, porous structure, exposed crystal plane, and surface chemistry etc. Synthesis technology plays a key role in determining the structural characteristics by controlling the rates of hydrolysis, condensation and crystallization and crystal growth. Solvothermal alcoholysis has received increasing interest in synthesizing metal oxides owing to the unique ability in controlling particle size, shape and crystal structure. This review aims to summarize the hierarchical TiO2 synthesized by solvothermal alcoholysis and display their enhanced activities in energy and environmental photocatalysis. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：72 / 86

页数：15

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