Aqueous Binder for Nanostructured Carbon Anode Materials for Li-Ion Batteries

被引:10
作者
Lis, Marcelina [1 ]
Chudzik, Krystian [1 ]
Bakierska, Monika [1 ]
Swietoslawski, Michal [1 ]
Gajewska, Marta [2 ]
Rutkowska, Malgorzata [1 ]
Molenda, Marcin [1 ]
机构
[1] Jagiellonian Univ, Fac Chem, PL-30387 Krakow, Poland
[2] AGH Univ Sci & Technol, Acad Ctr Mat & Nanotechnol, PL-30059 Krakow, Poland
关键词
POLYACRYLIC-ACID; HIGH-ENERGY; ELECTRODES; PARTICLES; SYSTEM;
D O I
10.1149/2.0591903jes
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Water soluble hydrophilic polymer poly-N-vinylformamide (PNVF) has been adopted as new binder for selected anode materials based on nanostructured carbon aerogels (CAGs) derived from different types of starch (rice, maize, potato) as well as for graphite as a reference. The results suggest that PNVF can be promising, fluorine free and volatile organic compounds (VOC) free binder for some anode materials especially when taking into consideration its beneficial properties, cost reduction as well as environmental friendliness. PNVF enhances chemical and physical interactions with tested carbons improving adhesion strength of the created composites and thus capacity retention of the formed electrodes during extensive cycling under high current load. Herein, we show that although the binder is only a small part of the entire electrode composition, it has a huge impact on the properties and efficiency of lithium-ion battery. Thereby, every anode material require properly selected binder for the suitable operation and performance of the cell. (C) The Author(s) 2019. Published by ECS.
引用
收藏
页码:A5354 / A5361
页数:8
相关论文
共 26 条
[21]  
Sheng-Shu H., 2018, 19 INT M LITH BATT I
[22]   Material and Structural Design of Novel Binder Systems for High-Energy, High-Power Lithium-Ion Batteries [J].
Shi, Ye ;
Zhou, Xingyi ;
Yu, Guihua .
ACCOUNTS OF CHEMICAL RESEARCH, 2017, 50 (11) :2642-2652
[23]   Cross-linked poly(acrylic acid)-carboxymethyl cellulose and styrene-butadiene rubber as an efficient binder system and its physicochemical effects on a high energy density graphite anode for Li-ion batteries [J].
Shin, Donghyeok ;
Park, Hyunjung ;
Paik, Ungyu .
ELECTROCHEMISTRY COMMUNICATIONS, 2017, 77 :103-106
[24]   A comparative study of different binders and their effects on electrochemical properties of LiMn2O4 cathode in lithium ion batteries [J].
Zhang, Zhian ;
Zeng, Tao ;
Lai, Yanqing ;
Jia, Ming ;
Li, Jie .
JOURNAL OF POWER SOURCES, 2014, 247 :1-8
[25]   Cycle performance improvement of LiFePO4 cathode with polyacrylic acid as binder [J].
Zhang, Zhian ;
Zeng, Tao ;
Qu, Changming ;
Lu, Hai ;
Jia, Ming ;
Lai, Yanqing ;
Li, Jie .
ELECTROCHIMICA ACTA, 2012, 80 :440-444
[26]   Better cycle stability and rate capability of high-voltage LiNi0.5Mn1.5O4 cathode using water soluble binder [J].
Zhong, Haoxiang ;
He, Jiarong ;
Zhang, Lingzhi .
MATERIALS RESEARCH BULLETIN, 2017, 93 :194-200